catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]

The title compound, [CuBr(C(9)H(9)N(5))](n), has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetra­zol-5-yl)pyridine. It is a new homometallic Cu(I) olefin coord­ination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra­zol-5-yl)pyridine ligands and bo...

Descripción completa

Detalles Bibliográficos
Autor principal: Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961586/
https://www.ncbi.nlm.nih.gov/pubmed/21202452
http://dx.doi.org/10.1107/S1600536808010313
_version_ 1782189017977061376
author Wang, Wei
author_facet Wang, Wei
author_sort Wang, Wei
collection PubMed
description The title compound, [CuBr(C(9)H(9)N(5))](n), has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetra­zol-5-yl)pyridine. It is a new homometallic Cu(I) olefin coord­ination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra­zol-5-yl)pyridine ligands and bonded to one terminal Br atom each. The organic ligand acts as a bidentate ligand connecting two neighboring Cu centers through the N atom of the pyridine ring and the double bond of the allyl group. A three-dimensional structure is formed through weak Cu—Br [3.1579 (8) Å], C—H⋯Br and C—H⋯N inter­actions.
format Text
id pubmed-2961586
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29615862010-12-30 catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine] Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuBr(C(9)H(9)N(5))](n), has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetra­zol-5-yl)pyridine. It is a new homometallic Cu(I) olefin coord­ination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra­zol-5-yl)pyridine ligands and bonded to one terminal Br atom each. The organic ligand acts as a bidentate ligand connecting two neighboring Cu centers through the N atom of the pyridine ring and the double bond of the allyl group. A three-dimensional structure is formed through weak Cu—Br [3.1579 (8) Å], C—H⋯Br and C—H⋯N inter­actions. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961586/ /pubmed/21202452 http://dx.doi.org/10.1107/S1600536808010313 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]
title catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]
title_full catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]
title_fullStr catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]
title_full_unstemmed catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]
title_short catena-Poly[[bromidocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]
title_sort catena-poly[[bromidocopper(i)]-μ-η(2),σ(1)-3-(2-allyl-2h-tetra­zol-5-yl)pyridine]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961586/
https://www.ncbi.nlm.nih.gov/pubmed/21202452
http://dx.doi.org/10.1107/S1600536808010313
work_keys_str_mv AT wangwei catenapolybromidocopperimē2s132allyl2htetrazol5ylpyridine

Ejemplares similares