Poly[[diaqua­[μ(4)-4,4′-carbonyl­bis(benzene-1,2-dicarboxyl­ato)]bis­(dipyrido[3,2-a:2′,3′-c]phenazine)dicadmium(II)] monohydrate]

In the title compound, {[Cd(2)(C(17)H(6)O(9))(C(18)H(10)N(4))(2)(H(2)O)(2)]·H(2)O}(n), the Cd(II) atom is seven-coordinated by five O atoms from two different 4,4′-carbonyl­bis(benzene-1,2-dicarboxyl­ate) (BPTC) anions and one water mol­ecule, and by two N atoms from one chelating dipyrido[3,2-a:2′,...

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Detalles Bibliográficos
Autores principales: Yuan, Xiao-Huan, Zhang, Wen-Zhi, Chu, Yan-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961587/
https://www.ncbi.nlm.nih.gov/pubmed/21202495
http://dx.doi.org/10.1107/S1600536808013676
Descripción
Sumario:In the title compound, {[Cd(2)(C(17)H(6)O(9))(C(18)H(10)N(4))(2)(H(2)O)(2)]·H(2)O}(n), the Cd(II) atom is seven-coordinated by five O atoms from two different 4,4′-carbonyl­bis(benzene-1,2-dicarboxyl­ate) (BPTC) anions and one water mol­ecule, and by two N atoms from one chelating dipyrido[3,2-a:2′,3′-c]phenazine (L) ligand in a distorted penta­gonal-bipyramidal geometry. The BPTC anions link the Cd(II) atoms, forming a one-dimensional chain structure. The L ligands are attached on both sides of the chain. A twofold rotation axis passes through the complex molecule. The crystal structure involves O—H⋯O hydrogen bonds.

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