(5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one

The title compound, C(15)H(18)N(2)O(3), is an example of an oxadiazinan-2-one with significant inter­action between the N(3)-acyl and N(4)-methyl groups. These steric inter­actions result in a large torsion angle between the two carbonyl groups, not present with acyl substituents with less steric de...

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Detalles Bibliográficos
Autores principales: Knott, Stanley A., Hitchcock, Shawn R., Ferrence, Gregory M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961593/
https://www.ncbi.nlm.nih.gov/pubmed/21202615
http://dx.doi.org/10.1107/S1600536808013986
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author Knott, Stanley A.
Hitchcock, Shawn R.
Ferrence, Gregory M.
author_facet Knott, Stanley A.
Hitchcock, Shawn R.
Ferrence, Gregory M.
author_sort Knott, Stanley A.
collection PubMed
description The title compound, C(15)H(18)N(2)O(3), is an example of an oxadiazinan-2-one with significant inter­action between the N(3)-acyl and N(4)-methyl groups. These steric inter­actions result in a large torsion angle between the two carbonyl groups, not present with acyl substituents with less steric demand.
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spelling pubmed-29615932010-12-30 (5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one Knott, Stanley A. Hitchcock, Shawn R. Ferrence, Gregory M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(18)N(2)O(3), is an example of an oxadiazinan-2-one with significant inter­action between the N(3)-acyl and N(4)-methyl groups. These steric inter­actions result in a large torsion angle between the two carbonyl groups, not present with acyl substituents with less steric demand. International Union of Crystallography 2008-05-17 /pmc/articles/PMC2961593/ /pubmed/21202615 http://dx.doi.org/10.1107/S1600536808013986 Text en © Knott et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Knott, Stanley A.
Hitchcock, Shawn R.
Ferrence, Gregory M.
(5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
title (5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
title_full (5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
title_fullStr (5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
title_full_unstemmed (5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
title_short (5S,6S)-4,5-Dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
title_sort (5s,6s)-4,5-dimethyl-3-methyl­acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961593/
https://www.ncbi.nlm.nih.gov/pubmed/21202615
http://dx.doi.org/10.1107/S1600536808013986
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