Dioxidobis(pentane-2,4-dionato-κ(2) O,O′)(pyridine-4-carbaldehyde oxime-κN (1))uranium(VI)

The title compound, [U(C(5)H(7)O(2))(2)O(2)(C(6)H(6)N(2)O)], exhibits a penta­gonal–bipyramidal coordination geometry around the U(VI) atom, involving two bidentate acetyl­acetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of t...

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Detalles Bibliográficos
Autores principales: Kawasaki, Takeshi, Kitazawa, Takafumi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961597/
https://www.ncbi.nlm.nih.gov/pubmed/21202477
http://dx.doi.org/10.1107/S1600536808012889
Descripción
Sumario:The title compound, [U(C(5)H(7)O(2))(2)O(2)(C(6)H(6)N(2)O)], exhibits a penta­gonal–bipyramidal coordination geometry around the U(VI) atom, involving two bidentate acetyl­acetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of the pyridine-4-carbaldehyde oxime ligand and the two O atoms of the acetyl­acetonate ions.

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