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Dioxidobis(pentane-2,4-dionato-κ(2) O,O′)(pyridine-4-carbaldehyde oxime-κN (1))uranium(VI)
The title compound, [U(C(5)H(7)O(2))(2)O(2)(C(6)H(6)N(2)O)], exhibits a pentagonal–bipyramidal coordination geometry around the U(VI) atom, involving two bidentate acetylacetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of t...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961597/ https://www.ncbi.nlm.nih.gov/pubmed/21202477 http://dx.doi.org/10.1107/S1600536808012889 |
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author | Kawasaki, Takeshi Kitazawa, Takafumi |
author_facet | Kawasaki, Takeshi Kitazawa, Takafumi |
author_sort | Kawasaki, Takeshi |
collection | PubMed |
description | The title compound, [U(C(5)H(7)O(2))(2)O(2)(C(6)H(6)N(2)O)], exhibits a pentagonal–bipyramidal coordination geometry around the U(VI) atom, involving two bidentate acetylacetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of the pyridine-4-carbaldehyde oxime ligand and the two O atoms of the acetylacetonate ions. |
format | Text |
id | pubmed-2961597 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29615972010-12-30 Dioxidobis(pentane-2,4-dionato-κ(2) O,O′)(pyridine-4-carbaldehyde oxime-κN (1))uranium(VI) Kawasaki, Takeshi Kitazawa, Takafumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [U(C(5)H(7)O(2))(2)O(2)(C(6)H(6)N(2)O)], exhibits a pentagonal–bipyramidal coordination geometry around the U(VI) atom, involving two bidentate acetylacetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of the pyridine-4-carbaldehyde oxime ligand and the two O atoms of the acetylacetonate ions. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961597/ /pubmed/21202477 http://dx.doi.org/10.1107/S1600536808012889 Text en © Kawasaki and Kitazawa 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kawasaki, Takeshi Kitazawa, Takafumi Dioxidobis(pentane-2,4-dionato-κ(2) O,O′)(pyridine-4-carbaldehyde oxime-κN (1))uranium(VI) |
title | Dioxidobis(pentane-2,4-dionato-κ(2)
O,O′)(pyridine-4-carbaldehyde oxime-κN
(1))uranium(VI) |
title_full | Dioxidobis(pentane-2,4-dionato-κ(2)
O,O′)(pyridine-4-carbaldehyde oxime-κN
(1))uranium(VI) |
title_fullStr | Dioxidobis(pentane-2,4-dionato-κ(2)
O,O′)(pyridine-4-carbaldehyde oxime-κN
(1))uranium(VI) |
title_full_unstemmed | Dioxidobis(pentane-2,4-dionato-κ(2)
O,O′)(pyridine-4-carbaldehyde oxime-κN
(1))uranium(VI) |
title_short | Dioxidobis(pentane-2,4-dionato-κ(2)
O,O′)(pyridine-4-carbaldehyde oxime-κN
(1))uranium(VI) |
title_sort | dioxidobis(pentane-2,4-dionato-κ(2)
o,o′)(pyridine-4-carbaldehyde oxime-κn
(1))uranium(vi) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961597/ https://www.ncbi.nlm.nih.gov/pubmed/21202477 http://dx.doi.org/10.1107/S1600536808012889 |
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