2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate

In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6 (1), 75.5 (1) and 80.69 (1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra­molecular C—H⋯S hydrogen bonds generate S(6)...

Descripción completa

Detalles Bibliográficos
Autores principales: Ravindran Durai Nayagam, B., Jebas, Samuel Robinson, Ravi Samuelraj, C., Schollmeyer, Dieter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961605/
https://www.ncbi.nlm.nih.gov/pubmed/21202559
http://dx.doi.org/10.1107/S1600536808013081
_version_ 1782189022392614912
author Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Ravi Samuelraj, C.
Schollmeyer, Dieter
author_facet Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Ravi Samuelraj, C.
Schollmeyer, Dieter
author_sort Ravindran Durai Nayagam, B.
collection PubMed
description In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6 (1), 75.5 (1) and 80.69 (1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra­molecular C—H⋯S hydrogen bonds generate S(6) ring motifs. The crystal structure is stabilized by intra­molecular C—H⋯S and inter­molecular C—H⋯O hydrogen bonds and weak C—H⋯π inter­actions.
format Text
id pubmed-2961605
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29616052010-12-30 2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate Ravindran Durai Nayagam, B. Jebas, Samuel Robinson Ravi Samuelraj, C. Schollmeyer, Dieter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6 (1), 75.5 (1) and 80.69 (1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra­molecular C—H⋯S hydrogen bonds generate S(6) ring motifs. The crystal structure is stabilized by intra­molecular C—H⋯S and inter­molecular C—H⋯O hydrogen bonds and weak C—H⋯π inter­actions. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961605/ /pubmed/21202559 http://dx.doi.org/10.1107/S1600536808013081 Text en © Ravindran Durai Nayagam et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Ravi Samuelraj, C.
Schollmeyer, Dieter
2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
title 2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
title_full 2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
title_fullStr 2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
title_full_unstemmed 2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
title_short 2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
title_sort 2,4,6-tris(1-oxo-2-pyridylsulfanylmeth­yl)mesitylene methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961605/
https://www.ncbi.nlm.nih.gov/pubmed/21202559
http://dx.doi.org/10.1107/S1600536808013081
work_keys_str_mv AT ravindrandurainayagamb 246tris1oxo2pyridylsulfanylmethylmesitylenemethanolsolvate
AT jebassamuelrobinson 246tris1oxo2pyridylsulfanylmethylmesitylenemethanolsolvate
AT ravisamuelrajc 246tris1oxo2pyridylsulfanylmethylmesitylenemethanolsolvate
AT schollmeyerdieter 246tris1oxo2pyridylsulfanylmethylmesitylenemethanolsolvate

Ejemplares similares