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2,3-Diamino­phenazine tetra­hydrate

The title compound, C(12)H(10)N(4)·4H(2)O, was obtained from a room-temperature solution of o-phenyl­enediamine and copper acetate. In the crystal structure, there are significant π–π stacking inter­actions, with a centroid–centroid separation of 3.575 (2) Å. In addition, inter­molecular O—H⋯O, N—H⋯...

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Detalles Bibliográficos
Autores principales: Li, Xiao-Feng, An, Yan, Yin, Yan-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961609/
https://www.ncbi.nlm.nih.gov/pubmed/21202528
http://dx.doi.org/10.1107/S1600536808009598
Descripción
Sumario:The title compound, C(12)H(10)N(4)·4H(2)O, was obtained from a room-temperature solution of o-phenyl­enediamine and copper acetate. In the crystal structure, there are significant π–π stacking inter­actions, with a centroid–centroid separation of 3.575 (2) Å. In addition, inter­molecular O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N hydrogen bonds link 2,3-diamino­phenazine mol­ecules and water mol­ecules, forming a three-dimensional framework.