2,3-Diamino­phenazine tetra­hydrate

The title compound, C(12)H(10)N(4)·4H(2)O, was obtained from a room-temperature solution of o-phenyl­enediamine and copper acetate. In the crystal structure, there are significant π–π stacking inter­actions, with a centroid–centroid separation of 3.575 (2) Å. In addition, inter­molecular O—H⋯O, N—H⋯...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Xiao-Feng, An, Yan, Yin, Yan-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961609/
https://www.ncbi.nlm.nih.gov/pubmed/21202528
http://dx.doi.org/10.1107/S1600536808009598
_version_ 1782189023351013376
author Li, Xiao-Feng
An, Yan
Yin, Yan-Sheng
author_facet Li, Xiao-Feng
An, Yan
Yin, Yan-Sheng
author_sort Li, Xiao-Feng
collection PubMed
description The title compound, C(12)H(10)N(4)·4H(2)O, was obtained from a room-temperature solution of o-phenyl­enediamine and copper acetate. In the crystal structure, there are significant π–π stacking inter­actions, with a centroid–centroid separation of 3.575 (2) Å. In addition, inter­molecular O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N hydrogen bonds link 2,3-diamino­phenazine mol­ecules and water mol­ecules, forming a three-dimensional framework.
format Text
id pubmed-2961609
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29616092010-12-30 2,3-Diamino­phenazine tetra­hydrate Li, Xiao-Feng An, Yan Yin, Yan-Sheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(10)N(4)·4H(2)O, was obtained from a room-temperature solution of o-phenyl­enediamine and copper acetate. In the crystal structure, there are significant π–π stacking inter­actions, with a centroid–centroid separation of 3.575 (2) Å. In addition, inter­molecular O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N hydrogen bonds link 2,3-diamino­phenazine mol­ecules and water mol­ecules, forming a three-dimensional framework. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961609/ /pubmed/21202528 http://dx.doi.org/10.1107/S1600536808009598 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xiao-Feng
An, Yan
Yin, Yan-Sheng
2,3-Diamino­phenazine tetra­hydrate
title 2,3-Diamino­phenazine tetra­hydrate
title_full 2,3-Diamino­phenazine tetra­hydrate
title_fullStr 2,3-Diamino­phenazine tetra­hydrate
title_full_unstemmed 2,3-Diamino­phenazine tetra­hydrate
title_short 2,3-Diamino­phenazine tetra­hydrate
title_sort 2,3-diamino­phenazine tetra­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961609/
https://www.ncbi.nlm.nih.gov/pubmed/21202528
http://dx.doi.org/10.1107/S1600536808009598
work_keys_str_mv AT lixiaofeng 23diaminophenazinetetrahydrate
AT anyan 23diaminophenazinetetrahydrate
AT yinyansheng 23diaminophenazinetetrahydrate

Ejemplares similares