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Bis(2-bromopyridinium) hexabromidostannate(IV)
The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnBr(6)], contains one cation and one half-anion. The [SnBr(6)](2−) anion is located on an inversion center and forms a quasi-regular octahedral arrangement. The crystal structure consists of two-dimensional supramolecular layers assemble...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961614/ https://www.ncbi.nlm.nih.gov/pubmed/21202444 http://dx.doi.org/10.1107/S1600536808012129 |
| _version_ | 1782189024540098560 |
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| author | Ali, Basem Fares Al-Far, Rawhi H. Haddad, Salim F. |
| author_facet | Ali, Basem Fares Al-Far, Rawhi H. Haddad, Salim F. |
| author_sort | Ali, Basem Fares |
| collection | PubMed |
| description | The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnBr(6)], contains one cation and one half-anion. The [SnBr(6)](2−) anion is located on an inversion center and forms a quasi-regular octahedral arrangement. The crystal structure consists of two-dimensional supramolecular layers assembled via hydrogen-bonding interactions of N—H⋯Br—Sn [D⋯A = 3.375 (13)–3.562 (13) Å and D—H⋯A = 127–142°, along with C—Br⋯Br synthons [3.667 (2) and 3.778 (3) Å]. These layers are parallel to the bc plane and built up from anions interacting extensively with the six surrounding cations. |
| format | Text |
| id | pubmed-2961614 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29616142010-12-30 Bis(2-bromopyridinium) hexabromidostannate(IV) Ali, Basem Fares Al-Far, Rawhi H. Haddad, Salim F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnBr(6)], contains one cation and one half-anion. The [SnBr(6)](2−) anion is located on an inversion center and forms a quasi-regular octahedral arrangement. The crystal structure consists of two-dimensional supramolecular layers assembled via hydrogen-bonding interactions of N—H⋯Br—Sn [D⋯A = 3.375 (13)–3.562 (13) Å and D—H⋯A = 127–142°, along with C—Br⋯Br synthons [3.667 (2) and 3.778 (3) Å]. These layers are parallel to the bc plane and built up from anions interacting extensively with the six surrounding cations. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961614/ /pubmed/21202444 http://dx.doi.org/10.1107/S1600536808012129 Text en © Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ali, Basem Fares Al-Far, Rawhi H. Haddad, Salim F. Bis(2-bromopyridinium) hexabromidostannate(IV) |
| title | Bis(2-bromopyridinium) hexabromidostannate(IV) |
| title_full | Bis(2-bromopyridinium) hexabromidostannate(IV) |
| title_fullStr | Bis(2-bromopyridinium) hexabromidostannate(IV) |
| title_full_unstemmed | Bis(2-bromopyridinium) hexabromidostannate(IV) |
| title_short | Bis(2-bromopyridinium) hexabromidostannate(IV) |
| title_sort | bis(2-bromopyridinium) hexabromidostannate(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961614/ https://www.ncbi.nlm.nih.gov/pubmed/21202444 http://dx.doi.org/10.1107/S1600536808012129 |
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