Methyl 3-[(E)-furfuryl­idene]dithio­carbazate

The mol­ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio­carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio­carbazate and furan units are located on opposite sides of the C=N double bond. The planar d...

Descripción completa

Detalles Bibliográficos
Autores principales: Shan, Shang, Wang, Shan-Heng, Xu, Ying-Li, Xie, Pei-Jin, Tian, Yu-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961615/
https://www.ncbi.nlm.nih.gov/pubmed/21202699
http://dx.doi.org/10.1107/S1600536808012506
Descripción
Sumario:The mol­ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio­carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio­carbazate and furan units are located on opposite sides of the C=N double bond. The planar dithio­carbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2 (1)°. Adjacent mol­ecules are linked by N—H⋯S hydrogen bonding to form a supra­molecular dimer across an inversion center.

Ejemplares similares