Methyl 3-[(E)-furfuryl­idene]dithio­carbazate

The mol­ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio­carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio­carbazate and furan units are located on opposite sides of the C=N double bond. The planar d...

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Autores principales: Shan, Shang, Wang, Shan-Heng, Xu, Ying-Li, Xie, Pei-Jin, Tian, Yu-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961615/
https://www.ncbi.nlm.nih.gov/pubmed/21202699
http://dx.doi.org/10.1107/S1600536808012506
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author Shan, Shang
Wang, Shan-Heng
Xu, Ying-Li
Xie, Pei-Jin
Tian, Yu-Liang
author_facet Shan, Shang
Wang, Shan-Heng
Xu, Ying-Li
Xie, Pei-Jin
Tian, Yu-Liang
author_sort Shan, Shang
collection PubMed
description The mol­ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio­carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio­carbazate and furan units are located on opposite sides of the C=N double bond. The planar dithio­carbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2 (1)°. Adjacent mol­ecules are linked by N—H⋯S hydrogen bonding to form a supra­molecular dimer across an inversion center.
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spelling pubmed-29616152010-12-30 Methyl 3-[(E)-furfuryl­idene]dithio­carbazate Shan, Shang Wang, Shan-Heng Xu, Ying-Li Xie, Pei-Jin Tian, Yu-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title Schiff base compound, C(7)H(8)N(2)OS(2), prepared by the reaction of methyl dithio­carbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithio­carbazate and furan units are located on opposite sides of the C=N double bond. The planar dithio­carbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2 (1)°. Adjacent mol­ecules are linked by N—H⋯S hydrogen bonding to form a supra­molecular dimer across an inversion center. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961615/ /pubmed/21202699 http://dx.doi.org/10.1107/S1600536808012506 Text en © Shan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shan, Shang
Wang, Shan-Heng
Xu, Ying-Li
Xie, Pei-Jin
Tian, Yu-Liang
Methyl 3-[(E)-furfuryl­idene]dithio­carbazate
title Methyl 3-[(E)-furfuryl­idene]dithio­carbazate
title_full Methyl 3-[(E)-furfuryl­idene]dithio­carbazate
title_fullStr Methyl 3-[(E)-furfuryl­idene]dithio­carbazate
title_full_unstemmed Methyl 3-[(E)-furfuryl­idene]dithio­carbazate
title_short Methyl 3-[(E)-furfuryl­idene]dithio­carbazate
title_sort methyl 3-[(e)-furfuryl­idene]dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961615/
https://www.ncbi.nlm.nih.gov/pubmed/21202699
http://dx.doi.org/10.1107/S1600536808012506
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AT xiepeijin methyl3efurfurylidenedithiocarbazate
AT tianyuliang methyl3efurfurylidenedithiocarbazate

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