Cargando…
1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene
The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis(phenylethynyl)benzene substituted by four methoxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 6...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961624/ https://www.ncbi.nlm.nih.gov/pubmed/21202588 http://dx.doi.org/10.1107/S1600536808013664 |
Sumario: | The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis(phenylethynyl)benzene substituted by four methoxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 67.7 (1)° between the central benzene ring and the terminal benzene rings. In the crystal structure, molecules form a zigzag molecular network due to π–π [the interplanar and centroid–centroid distances between the benzene rings are 3.50 (1) and 3.57 (1) Å, respectively] and C—H⋯π interactions (2.75 Å). Introduction of the four methoxy groups results in the supramolecular architecture. |
---|