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1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene
The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis(phenylethynyl)benzene substituted by four methoxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 6...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961624/ https://www.ncbi.nlm.nih.gov/pubmed/21202588 http://dx.doi.org/10.1107/S1600536808013664 |
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author | Ono, Katsuhiko Tsukamoto, Kenichi Tomura, Masaaki Saito, Katsuhiro |
author_facet | Ono, Katsuhiko Tsukamoto, Kenichi Tomura, Masaaki Saito, Katsuhiro |
author_sort | Ono, Katsuhiko |
collection | PubMed |
description | The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis(phenylethynyl)benzene substituted by four methoxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 67.7 (1)° between the central benzene ring and the terminal benzene rings. In the crystal structure, molecules form a zigzag molecular network due to π–π [the interplanar and centroid–centroid distances between the benzene rings are 3.50 (1) and 3.57 (1) Å, respectively] and C—H⋯π interactions (2.75 Å). Introduction of the four methoxy groups results in the supramolecular architecture. |
format | Text |
id | pubmed-2961624 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616242010-12-30 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene Ono, Katsuhiko Tsukamoto, Kenichi Tomura, Masaaki Saito, Katsuhiro Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis(phenylethynyl)benzene substituted by four methoxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 67.7 (1)° between the central benzene ring and the terminal benzene rings. In the crystal structure, molecules form a zigzag molecular network due to π–π [the interplanar and centroid–centroid distances between the benzene rings are 3.50 (1) and 3.57 (1) Å, respectively] and C—H⋯π interactions (2.75 Å). Introduction of the four methoxy groups results in the supramolecular architecture. International Union of Crystallography 2008-05-14 /pmc/articles/PMC2961624/ /pubmed/21202588 http://dx.doi.org/10.1107/S1600536808013664 Text en © Ono et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ono, Katsuhiko Tsukamoto, Kenichi Tomura, Masaaki Saito, Katsuhiro 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
title | 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
title_full | 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
title_fullStr | 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
title_full_unstemmed | 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
title_short | 1,4-Bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
title_sort | 1,4-bis[(2,6-dimethoxyphenyl)ethynyl]benzene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961624/ https://www.ncbi.nlm.nih.gov/pubmed/21202588 http://dx.doi.org/10.1107/S1600536808013664 |
work_keys_str_mv | AT onokatsuhiko 14bis26dimethoxyphenylethynylbenzene AT tsukamotokenichi 14bis26dimethoxyphenylethynylbenzene AT tomuramasaaki 14bis26dimethoxyphenylethynylbenzene AT saitokatsuhiro 14bis26dimethoxyphenylethynylbenzene |