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1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene

The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis­(phenyl­ethyn­yl)benzene substituted by four meth­oxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 6...

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Detalles Bibliográficos
Autores principales: Ono, Katsuhiko, Tsukamoto, Kenichi, Tomura, Masaaki, Saito, Katsuhiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961624/
https://www.ncbi.nlm.nih.gov/pubmed/21202588
http://dx.doi.org/10.1107/S1600536808013664
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author Ono, Katsuhiko
Tsukamoto, Kenichi
Tomura, Masaaki
Saito, Katsuhiro
author_facet Ono, Katsuhiko
Tsukamoto, Kenichi
Tomura, Masaaki
Saito, Katsuhiro
author_sort Ono, Katsuhiko
collection PubMed
description The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis­(phenyl­ethyn­yl)benzene substituted by four meth­oxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 67.7 (1)° between the central benzene ring and the terminal benzene rings. In the crystal structure, mol­ecules form a zigzag mol­ecular network due to π–π [the inter­planar and centroid–centroid distances between the benzene rings are 3.50 (1) and 3.57 (1) Å, respectively] and C—H⋯π inter­actions (2.75 Å). Introduction of the four meth­oxy groups results in the supra­molecular architecture.
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spelling pubmed-29616242010-12-30 1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene Ono, Katsuhiko Tsukamoto, Kenichi Tomura, Masaaki Saito, Katsuhiro Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(22)O(4), is a derivative of 1,4-bis­(phenyl­ethyn­yl)benzene substituted by four meth­oxy groups at the terminal benzene rings. The asymmetric unit consists of two half-molecules; one centrosymmetric molecule is planar but the other is non-planar, with dihedral angles of 67.7 (1)° between the central benzene ring and the terminal benzene rings. In the crystal structure, mol­ecules form a zigzag mol­ecular network due to π–π [the inter­planar and centroid–centroid distances between the benzene rings are 3.50 (1) and 3.57 (1) Å, respectively] and C—H⋯π inter­actions (2.75 Å). Introduction of the four meth­oxy groups results in the supra­molecular architecture. International Union of Crystallography 2008-05-14 /pmc/articles/PMC2961624/ /pubmed/21202588 http://dx.doi.org/10.1107/S1600536808013664 Text en © Ono et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ono, Katsuhiko
Tsukamoto, Kenichi
Tomura, Masaaki
Saito, Katsuhiro
1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
title 1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
title_full 1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
title_fullStr 1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
title_full_unstemmed 1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
title_short 1,4-Bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
title_sort 1,4-bis[(2,6-dimethoxy­phen­yl)ethyn­yl]benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961624/
https://www.ncbi.nlm.nih.gov/pubmed/21202588
http://dx.doi.org/10.1107/S1600536808013664
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