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Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]

In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxyl­ate O atoms from different chdc ligands and two...

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Detalles Bibliográficos
Autores principales: Zhang, Wen-Zhi, Yuan, Xiao-Huan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961629/
https://www.ncbi.nlm.nih.gov/pubmed/21202471
http://dx.doi.org/10.1107/S1600536808012737
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author Zhang, Wen-Zhi
Yuan, Xiao-Huan
author_facet Zhang, Wen-Zhi
Yuan, Xiao-Huan
author_sort Zhang, Wen-Zhi
collection PubMed
description In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxyl­ate O atoms from different chdc ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine (L) ligand, while the second Mn atom is six-coordinate, binding to six carboxyl­ate O atoms from different chdc ligands. The cis-chdc ligands bridge the trinuclear Mn(II) clusters, forming chains, which are further linked into a three-dimensional network.
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spelling pubmed-29616292010-12-30 Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] Zhang, Wen-Zhi Yuan, Xiao-Huan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxyl­ate O atoms from different chdc ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine (L) ligand, while the second Mn atom is six-coordinate, binding to six carboxyl­ate O atoms from different chdc ligands. The cis-chdc ligands bridge the trinuclear Mn(II) clusters, forming chains, which are further linked into a three-dimensional network. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961629/ /pubmed/21202471 http://dx.doi.org/10.1107/S1600536808012737 Text en © Zhang and Yuan 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wen-Zhi
Yuan, Xiao-Huan
Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
title Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
title_full Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
title_fullStr Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
title_full_unstemmed Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
title_short Poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
title_sort poly[di-μ-cis-cyclo­hexane-1,4-dicarboxyl­ato-μ-trans-cyclo­hexane-1,4-dicarboxyl­ato-bis­[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961629/
https://www.ncbi.nlm.nih.gov/pubmed/21202471
http://dx.doi.org/10.1107/S1600536808012737
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