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Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]
In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxylate O atoms from different chdc ligands and two...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961629/ https://www.ncbi.nlm.nih.gov/pubmed/21202471 http://dx.doi.org/10.1107/S1600536808012737 |
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author | Zhang, Wen-Zhi Yuan, Xiao-Huan |
author_facet | Zhang, Wen-Zhi Yuan, Xiao-Huan |
author_sort | Zhang, Wen-Zhi |
collection | PubMed |
description | In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxylate O atoms from different chdc ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine (L) ligand, while the second Mn atom is six-coordinate, binding to six carboxylate O atoms from different chdc ligands. The cis-chdc ligands bridge the trinuclear Mn(II) clusters, forming chains, which are further linked into a three-dimensional network. |
format | Text |
id | pubmed-2961629 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616292010-12-30 Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] Zhang, Wen-Zhi Yuan, Xiao-Huan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxylate O atoms from different chdc ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine (L) ligand, while the second Mn atom is six-coordinate, binding to six carboxylate O atoms from different chdc ligands. The cis-chdc ligands bridge the trinuclear Mn(II) clusters, forming chains, which are further linked into a three-dimensional network. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961629/ /pubmed/21202471 http://dx.doi.org/10.1107/S1600536808012737 Text en © Zhang and Yuan 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Wen-Zhi Yuan, Xiao-Huan Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] |
title | Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] |
title_full | Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] |
title_fullStr | Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] |
title_full_unstemmed | Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] |
title_short | Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] |
title_sort | poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961629/ https://www.ncbi.nlm.nih.gov/pubmed/21202471 http://dx.doi.org/10.1107/S1600536808012737 |
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