{2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)

In the title complex, [CoCl(2)(C(21)H(19)N(3))], the Co(II) atom is coordinated by one pyridine and two imine N atoms and by two chloride anions in a distorted trigonal bipyramidal geometry. The structure exhibits a pseudo-mirror plane through the metal atom, two chloride anions and the pyridine rin...

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Detalles Bibliográficos
Autores principales: Li, Xiao-Gang, Zhong, Di-Chang, He, Ren, Guo, Hui-Rui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961630/
https://www.ncbi.nlm.nih.gov/pubmed/21202475
http://dx.doi.org/10.1107/S1600536808013007
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author Li, Xiao-Gang
Zhong, Di-Chang
He, Ren
Guo, Hui-Rui
author_facet Li, Xiao-Gang
Zhong, Di-Chang
He, Ren
Guo, Hui-Rui
author_sort Li, Xiao-Gang
collection PubMed
description In the title complex, [CoCl(2)(C(21)H(19)N(3))], the Co(II) atom is coordinated by one pyridine and two imine N atoms and by two chloride anions in a distorted trigonal bipyramidal geometry. The structure exhibits a pseudo-mirror plane through the metal atom, two chloride anions and the pyridine ring. In the crystal structure, the complexes are connected via inter­molecular C—H⋯Cl hydrogen bonding.
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spelling pubmed-29616302010-12-30 {2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II) Li, Xiao-Gang Zhong, Di-Chang He, Ren Guo, Hui-Rui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoCl(2)(C(21)H(19)N(3))], the Co(II) atom is coordinated by one pyridine and two imine N atoms and by two chloride anions in a distorted trigonal bipyramidal geometry. The structure exhibits a pseudo-mirror plane through the metal atom, two chloride anions and the pyridine ring. In the crystal structure, the complexes are connected via inter­molecular C—H⋯Cl hydrogen bonding. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961630/ /pubmed/21202475 http://dx.doi.org/10.1107/S1600536808013007 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xiao-Gang
Zhong, Di-Chang
He, Ren
Guo, Hui-Rui
{2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)
title {2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)
title_full {2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)
title_fullStr {2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)
title_full_unstemmed {2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)
title_short {2,6-Bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) N,N′,N′′}dichloridocobalt(II)
title_sort {2,6-bis[1-(phenyl­imino)eth­yl]pyridine-κ(3) n,n′,n′′}dichloridocobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961630/
https://www.ncbi.nlm.nih.gov/pubmed/21202475
http://dx.doi.org/10.1107/S1600536808013007
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AT heren 26bis1phenyliminoethylpyridinek3nnndichloridocobaltii
AT guohuirui 26bis1phenyliminoethylpyridinek3nnndichloridocobaltii

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