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Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate

In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionate ligand, and by the O atom from a water mol­ecule in a square-planar coordination. There...

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Detalles Bibliográficos
Autores principales: Liu, Zheng, Wang, Yong Liao, Wang, Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961633/
https://www.ncbi.nlm.nih.gov/pubmed/21202449
http://dx.doi.org/10.1107/S1600536808012038
Descripción
Sumario:In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionate ligand, and by the O atom from a water mol­ecule in a square-planar coordination. There are two formula units in the asymmetric unit. Molecules are further assembled into a three-dimensional network through C—H⋯Cl contacts, a Cu⋯Cl weak inter­action [3.161 (2) Å], O—H⋯O and C—H⋯O hydrogen bonds. The three water mol­ecules of the asymmetric unit are distributed over five positions with one full and two approximately half occupancies, while a tyrosine side chain in one of the complex mol­ecules is disordered over two positions [occupancies 0.507 (5) and 0.493 (5)].