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Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate

In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionate ligand, and by the O atom from a water mol­ecule in a square-planar coordination. There...

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Detalles Bibliográficos
Autores principales: Liu, Zheng, Wang, Yong Liao, Wang, Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961633/
https://www.ncbi.nlm.nih.gov/pubmed/21202449
http://dx.doi.org/10.1107/S1600536808012038
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author Liu, Zheng
Wang, Yong Liao
Wang, Li
author_facet Liu, Zheng
Wang, Yong Liao
Wang, Li
author_sort Liu, Zheng
collection PubMed
description In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionate ligand, and by the O atom from a water mol­ecule in a square-planar coordination. There are two formula units in the asymmetric unit. Molecules are further assembled into a three-dimensional network through C—H⋯Cl contacts, a Cu⋯Cl weak inter­action [3.161 (2) Å], O—H⋯O and C—H⋯O hydrogen bonds. The three water mol­ecules of the asymmetric unit are distributed over five positions with one full and two approximately half occupancies, while a tyrosine side chain in one of the complex mol­ecules is disordered over two positions [occupancies 0.507 (5) and 0.493 (5)].
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spelling pubmed-29616332010-12-30 Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate Liu, Zheng Wang, Yong Liao Wang, Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionate ligand, and by the O atom from a water mol­ecule in a square-planar coordination. There are two formula units in the asymmetric unit. Molecules are further assembled into a three-dimensional network through C—H⋯Cl contacts, a Cu⋯Cl weak inter­action [3.161 (2) Å], O—H⋯O and C—H⋯O hydrogen bonds. The three water mol­ecules of the asymmetric unit are distributed over five positions with one full and two approximately half occupancies, while a tyrosine side chain in one of the complex mol­ecules is disordered over two positions [occupancies 0.507 (5) and 0.493 (5)]. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961633/ /pubmed/21202449 http://dx.doi.org/10.1107/S1600536808012038 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Zheng
Wang, Yong Liao
Wang, Li
Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
title Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
title_full Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
title_fullStr Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
title_full_unstemmed Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
title_short Aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
title_sort aqua­{2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-(4-hydroxy­phen­yl)propionato-κ(3) o (1),n,o (2)}copper(ii) sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961633/
https://www.ncbi.nlm.nih.gov/pubmed/21202449
http://dx.doi.org/10.1107/S1600536808012038
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