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Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate
In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionate ligand, and by the O atom from a water molecule in a square-planar coordination. There...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961633/ https://www.ncbi.nlm.nih.gov/pubmed/21202449 http://dx.doi.org/10.1107/S1600536808012038 |
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author | Liu, Zheng Wang, Yong Liao Wang, Li |
author_facet | Liu, Zheng Wang, Yong Liao Wang, Li |
author_sort | Liu, Zheng |
collection | PubMed |
description | In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionate ligand, and by the O atom from a water molecule in a square-planar coordination. There are two formula units in the asymmetric unit. Molecules are further assembled into a three-dimensional network through C—H⋯Cl contacts, a Cu⋯Cl weak interaction [3.161 (2) Å], O—H⋯O and C—H⋯O hydrogen bonds. The three water molecules of the asymmetric unit are distributed over five positions with one full and two approximately half occupancies, while a tyrosine side chain in one of the complex molecules is disordered over two positions [occupancies 0.507 (5) and 0.493 (5)]. |
format | Text |
id | pubmed-2961633 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616332010-12-30 Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate Liu, Zheng Wang, Yong Liao Wang, Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(11)Cl(2)NO(4))(H(2)O)]·1.5H(2)O, the Cu(II) atom is coordinated by two O atoms and one N atom from the 2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionate ligand, and by the O atom from a water molecule in a square-planar coordination. There are two formula units in the asymmetric unit. Molecules are further assembled into a three-dimensional network through C—H⋯Cl contacts, a Cu⋯Cl weak interaction [3.161 (2) Å], O—H⋯O and C—H⋯O hydrogen bonds. The three water molecules of the asymmetric unit are distributed over five positions with one full and two approximately half occupancies, while a tyrosine side chain in one of the complex molecules is disordered over two positions [occupancies 0.507 (5) and 0.493 (5)]. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961633/ /pubmed/21202449 http://dx.doi.org/10.1107/S1600536808012038 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Zheng Wang, Yong Liao Wang, Li Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3) O (1),N,O (2)}copper(II) sesquihydrate |
title | Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3)
O
(1),N,O
(2)}copper(II) sesquihydrate |
title_full | Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3)
O
(1),N,O
(2)}copper(II) sesquihydrate |
title_fullStr | Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3)
O
(1),N,O
(2)}copper(II) sesquihydrate |
title_full_unstemmed | Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3)
O
(1),N,O
(2)}copper(II) sesquihydrate |
title_short | Aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3)
O
(1),N,O
(2)}copper(II) sesquihydrate |
title_sort | aqua{2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-(4-hydroxyphenyl)propionato-κ(3)
o
(1),n,o
(2)}copper(ii) sesquihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961633/ https://www.ncbi.nlm.nih.gov/pubmed/21202449 http://dx.doi.org/10.1107/S1600536808012038 |
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