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catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]

The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged...

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Detalles Bibliográficos
Autor principal: Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961636/
https://www.ncbi.nlm.nih.gov/pubmed/21202785
http://dx.doi.org/10.1107/S1600536808017820
Descripción
Sumario:The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged by two olefin ligands. The asymmetric unit contains one-half of the monomer, the complete monomer having twofold rotation symmetry. The coordination environment of Cu(I) is slightly distorted tetra­hedral, with coordination sites being two μ(2)-Cl atoms, one pyridine N atom of an organic ligand and one allylic double bond of a symmetry-related ligand. Each organic mol­ecule behaves as a bidentate ligand, connecting two neighboring Cu(2)Cl(2) dimers in the polymeric chain, which runs along [010].