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catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]]
The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetrazol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961636/ https://www.ncbi.nlm.nih.gov/pubmed/21202785 http://dx.doi.org/10.1107/S1600536808017820 |
Sumario: | The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetrazol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged by two olefin ligands. The asymmetric unit contains one-half of the monomer, the complete monomer having twofold rotation symmetry. The coordination environment of Cu(I) is slightly distorted tetrahedral, with coordination sites being two μ(2)-Cl atoms, one pyridine N atom of an organic ligand and one allylic double bond of a symmetry-related ligand. Each organic molecule behaves as a bidentate ligand, connecting two neighboring Cu(2)Cl(2) dimers in the polymeric chain, which runs along [010]. |
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