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catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]

The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged...

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Detalles Bibliográficos
Autor principal: Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961636/
https://www.ncbi.nlm.nih.gov/pubmed/21202785
http://dx.doi.org/10.1107/S1600536808017820
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author Wang, Wei
author_facet Wang, Wei
author_sort Wang, Wei
collection PubMed
description The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged by two olefin ligands. The asymmetric unit contains one-half of the monomer, the complete monomer having twofold rotation symmetry. The coordination environment of Cu(I) is slightly distorted tetra­hedral, with coordination sites being two μ(2)-Cl atoms, one pyridine N atom of an organic ligand and one allylic double bond of a symmetry-related ligand. Each organic mol­ecule behaves as a bidentate ligand, connecting two neighboring Cu(2)Cl(2) dimers in the polymeric chain, which runs along [010].
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spelling pubmed-29616362010-12-30 catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]] Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged by two olefin ligands. The asymmetric unit contains one-half of the monomer, the complete monomer having twofold rotation symmetry. The coordination environment of Cu(I) is slightly distorted tetra­hedral, with coordination sites being two μ(2)-Cl atoms, one pyridine N atom of an organic ligand and one allylic double bond of a symmetry-related ligand. Each organic mol­ecule behaves as a bidentate ligand, connecting two neighboring Cu(2)Cl(2) dimers in the polymeric chain, which runs along [010]. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961636/ /pubmed/21202785 http://dx.doi.org/10.1107/S1600536808017820 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_full catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_fullStr catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_full_unstemmed catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_short catena-Poly[[di-μ-chlorido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_sort catena-poly[[di-μ-chlorido-dicopper(i)]bis­[μ-η(2),σ(1)-4-(2-allyl-2h-tetra­zol-5-yl)pyridine]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961636/
https://www.ncbi.nlm.nih.gov/pubmed/21202785
http://dx.doi.org/10.1107/S1600536808017820
work_keys_str_mv AT wangwei catenapolydimchloridodicopperibismē2s142allyl2htetrazol5ylpyridine