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catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]]
The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetrazol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961636/ https://www.ncbi.nlm.nih.gov/pubmed/21202785 http://dx.doi.org/10.1107/S1600536808017820 |
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author | Wang, Wei |
author_facet | Wang, Wei |
author_sort | Wang, Wei |
collection | PubMed |
description | The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetrazol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged by two olefin ligands. The asymmetric unit contains one-half of the monomer, the complete monomer having twofold rotation symmetry. The coordination environment of Cu(I) is slightly distorted tetrahedral, with coordination sites being two μ(2)-Cl atoms, one pyridine N atom of an organic ligand and one allylic double bond of a symmetry-related ligand. Each organic molecule behaves as a bidentate ligand, connecting two neighboring Cu(2)Cl(2) dimers in the polymeric chain, which runs along [010]. |
format | Text |
id | pubmed-2961636 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616362010-12-30 catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymer, [Cu(2)Cl(2)(C(9)H(9)N(5))(2)](n), has been prepared by the solvothermal treatment of CuCl with 4-(2-allyl-2H-tetrazol-5-yl)pyridine. The crystal structure shows that the title compound is a homometallic Cu(I)–olefin coordination polymer, in which the Cu(2)Cl(2) nodes are bridged by two olefin ligands. The asymmetric unit contains one-half of the monomer, the complete monomer having twofold rotation symmetry. The coordination environment of Cu(I) is slightly distorted tetrahedral, with coordination sites being two μ(2)-Cl atoms, one pyridine N atom of an organic ligand and one allylic double bond of a symmetry-related ligand. Each organic molecule behaves as a bidentate ligand, connecting two neighboring Cu(2)Cl(2) dimers in the polymeric chain, which runs along [010]. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961636/ /pubmed/21202785 http://dx.doi.org/10.1107/S1600536808017820 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Wei catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] |
title |
catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] |
title_full |
catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] |
title_fullStr |
catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] |
title_full_unstemmed |
catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] |
title_short |
catena-Poly[[di-μ-chlorido-dicopper(I)]bis[μ-η(2),σ(1)-4-(2-allyl-2H-tetrazol-5-yl)pyridine]] |
title_sort | catena-poly[[di-μ-chlorido-dicopper(i)]bis[μ-η(2),σ(1)-4-(2-allyl-2h-tetrazol-5-yl)pyridine]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961636/ https://www.ncbi.nlm.nih.gov/pubmed/21202785 http://dx.doi.org/10.1107/S1600536808017820 |
work_keys_str_mv | AT wangwei catenapolydimchloridodicopperibismē2s142allyl2htetrazol5ylpyridine |