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Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961648/ https://www.ncbi.nlm.nih.gov/pubmed/21202800 http://dx.doi.org/10.1107/S160053680801787X |
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author | Romanowski, Grzegorz Sikorski, Artur Wojtczak, Andrzej |
author_facet | Romanowski, Grzegorz Sikorski, Artur Wojtczak, Andrzej |
author_sort | Romanowski, Grzegorz |
collection | PubMed |
description | In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octahedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure, there are N—H⋯O, C—H⋯O and C—H⋯π hydrogen bonds, and π–π interactions. |
format | Text |
id | pubmed-2961648 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616482010-12-30 Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V)) Romanowski, Grzegorz Sikorski, Artur Wojtczak, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octahedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure, there are N—H⋯O, C—H⋯O and C—H⋯π hydrogen bonds, and π–π interactions. International Union of Crystallography 2008-06-21 /pmc/articles/PMC2961648/ /pubmed/21202800 http://dx.doi.org/10.1107/S160053680801787X Text en © Romanowski et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Romanowski, Grzegorz Sikorski, Artur Wojtczak, Andrzej Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V)) |
title | Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3)
N,N′,O}oxidovanadium(V)) |
title_full | Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3)
N,N′,O}oxidovanadium(V)) |
title_fullStr | Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3)
N,N′,O}oxidovanadium(V)) |
title_full_unstemmed | Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3)
N,N′,O}oxidovanadium(V)) |
title_short | Di-μ-oxido-bis({(R)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3)
N,N′,O}oxidovanadium(V)) |
title_sort | di-μ-oxido-bis({(r)-(–)-2-[1-(2-aminopropylimino)ethyl]-1-naphtholato-κ(3)
n,n′,o}oxidovanadium(v)) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961648/ https://www.ncbi.nlm.nih.gov/pubmed/21202800 http://dx.doi.org/10.1107/S160053680801787X |
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