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Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))

In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted...

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Detalles Bibliográficos
Autores principales: Romanowski, Grzegorz, Sikorski, Artur, Wojtczak, Andrzej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961648/
https://www.ncbi.nlm.nih.gov/pubmed/21202800
http://dx.doi.org/10.1107/S160053680801787X
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author Romanowski, Grzegorz
Sikorski, Artur
Wojtczak, Andrzej
author_facet Romanowski, Grzegorz
Sikorski, Artur
Wojtczak, Andrzej
author_sort Romanowski, Grzegorz
collection PubMed
description In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octa­hedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure, there are N—H⋯O, C—H⋯O and C—H⋯π hydrogen bonds, and π–π inter­actions.
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spelling pubmed-29616482010-12-30 Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V)) Romanowski, Grzegorz Sikorski, Artur Wojtczak, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octa­hedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure, there are N—H⋯O, C—H⋯O and C—H⋯π hydrogen bonds, and π–π inter­actions. International Union of Crystallography 2008-06-21 /pmc/articles/PMC2961648/ /pubmed/21202800 http://dx.doi.org/10.1107/S160053680801787X Text en © Romanowski et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Romanowski, Grzegorz
Sikorski, Artur
Wojtczak, Andrzej
Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
title Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
title_full Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
title_fullStr Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
title_full_unstemmed Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
title_short Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) N,N′,O}oxidovanadium(V))
title_sort di-μ-oxido-bis­({(r)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ(3) n,n′,o}oxidovanadium(v))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961648/
https://www.ncbi.nlm.nih.gov/pubmed/21202800
http://dx.doi.org/10.1107/S160053680801787X
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