Diazido­bis(2,2′-biimidazole)iron(II)

In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa­hedron. The non-H atoms of the equatorial plane are coplanar, with a mean dev...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Mu, Chunhua, Kong, Binbin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961650/
https://www.ncbi.nlm.nih.gov/pubmed/21202805
http://dx.doi.org/10.1107/S1600536808018539
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author Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_facet Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_sort Hao, Lujiang
collection PubMed
description In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa­hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The Fe(II) cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-mol­ecule.
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spelling pubmed-29616502010-12-30 Diazido­bis(2,2′-biimidazole)iron(II) Hao, Lujiang Mu, Chunhua Kong, Binbin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa­hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The Fe(II) cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-mol­ecule. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961650/ /pubmed/21202805 http://dx.doi.org/10.1107/S1600536808018539 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Mu, Chunhua
Kong, Binbin
Diazido­bis(2,2′-biimidazole)iron(II)
title Diazido­bis(2,2′-biimidazole)iron(II)
title_full Diazido­bis(2,2′-biimidazole)iron(II)
title_fullStr Diazido­bis(2,2′-biimidazole)iron(II)
title_full_unstemmed Diazido­bis(2,2′-biimidazole)iron(II)
title_short Diazido­bis(2,2′-biimidazole)iron(II)
title_sort diazido­bis(2,2′-biimidazole)iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961650/
https://www.ncbi.nlm.nih.gov/pubmed/21202805
http://dx.doi.org/10.1107/S1600536808018539
work_keys_str_mv AT haolujiang diazidobis22biimidazoleironii
AT muchunhua diazidobis22biimidazoleironii
AT kongbinbin diazidobis22biimidazoleironii

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