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Dibromido{2-[2-(piperidinium-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate
The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex molecule and a solvent water molecule. The Zn(II) atom is four-coordinated in an approximately tetrahedral geometry, binding to the imine N and phenolate O atoms of...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961651/ https://www.ncbi.nlm.nih.gov/pubmed/21202736 http://dx.doi.org/10.1107/S1600536808015730 |
Sumario: | The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex molecule and a solvent water molecule. The Zn(II) atom is four-coordinated in an approximately tetrahedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(−) anions. In the crystal structure, molecules are linked through intermolecular O—H⋯Br and O—H⋯O hydrogen bonds, forming chains running along the b axis. |
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