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Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate

The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol­ecule and a solvent water mol­ecule. The Zn(II) atom is four-coordinated in an approximately tetra­hedral geometry, binding to the imine N and phenolate O atoms of...

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Detalles Bibliográficos
Autores principales: Wei, Yi-Jun, Wang, Feng-Wu, Zhu, Qi-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961651/
https://www.ncbi.nlm.nih.gov/pubmed/21202736
http://dx.doi.org/10.1107/S1600536808015730
Descripción
Sumario:The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol­ecule and a solvent water mol­ecule. The Zn(II) atom is four-coordinated in an approximately tetra­hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(−) anions. In the crystal structure, mol­ecules are linked through inter­molecular O—H⋯Br and O—H⋯O hydrogen bonds, forming chains running along the b axis.