Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate

The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol­ecule and a solvent water mol­ecule. The Zn(II) atom is four-coordinated in an approximately tetra­hedral geometry, binding to the imine N and phenolate O atoms of...

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Detalles Bibliográficos
Autores principales: Wei, Yi-Jun, Wang, Feng-Wu, Zhu, Qi-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961651/
https://www.ncbi.nlm.nih.gov/pubmed/21202736
http://dx.doi.org/10.1107/S1600536808015730
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author Wei, Yi-Jun
Wang, Feng-Wu
Zhu, Qi-Yong
author_facet Wei, Yi-Jun
Wang, Feng-Wu
Zhu, Qi-Yong
author_sort Wei, Yi-Jun
collection PubMed
description The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol­ecule and a solvent water mol­ecule. The Zn(II) atom is four-coordinated in an approximately tetra­hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(−) anions. In the crystal structure, mol­ecules are linked through inter­molecular O—H⋯Br and O—H⋯O hydrogen bonds, forming chains running along the b axis.
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spelling pubmed-29616512010-12-30 Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate Wei, Yi-Jun Wang, Feng-Wu Zhu, Qi-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol­ecule and a solvent water mol­ecule. The Zn(II) atom is four-coordinated in an approximately tetra­hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(−) anions. In the crystal structure, mol­ecules are linked through inter­molecular O—H⋯Br and O—H⋯O hydrogen bonds, forming chains running along the b axis. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961651/ /pubmed/21202736 http://dx.doi.org/10.1107/S1600536808015730 Text en © Wei et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Yi-Jun
Wang, Feng-Wu
Zhu, Qi-Yong
Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate
title Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate
title_full Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate
title_fullStr Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate
title_full_unstemmed Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate
title_short Dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate
title_sort dibromido{2-[2-(piperidinium-1-yl)ethyl­imino­meth­yl]phenolato}zinc(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961651/
https://www.ncbi.nlm.nih.gov/pubmed/21202736
http://dx.doi.org/10.1107/S1600536808015730
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