trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)

In the centrosymmetric title compound, [Ni(N(3))(2)(C(22)H(34)N(6))], the Ni(II) ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetra­gonally distorted octa­hedron. An N—H⋯N h...

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Detalles Bibliográficos
Autores principales: Shin, Jong Won, Min, Kil Sik
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961652/
https://www.ncbi.nlm.nih.gov/pubmed/21202794
http://dx.doi.org/10.1107/S1600536808018199
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author Shin, Jong Won
Min, Kil Sik
author_facet Shin, Jong Won
Min, Kil Sik
author_sort Shin, Jong Won
collection PubMed
description In the centrosymmetric title compound, [Ni(N(3))(2)(C(22)H(34)N(6))], the Ni(II) ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetra­gonally distorted octa­hedron. An N—H⋯N hydrogen-bonding inter­action between the secondary amine N atom of the macrocycle and an adjacent azide ion gives rise to a chain structure.
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spelling pubmed-29616522010-12-30 trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II) Shin, Jong Won Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Ni(N(3))(2)(C(22)H(34)N(6))], the Ni(II) ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetra­gonally distorted octa­hedron. An N—H⋯N hydrogen-bonding inter­action between the secondary amine N atom of the macrocycle and an adjacent azide ion gives rise to a chain structure. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961652/ /pubmed/21202794 http://dx.doi.org/10.1107/S1600536808018199 Text en © Shin and Min 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shin, Jong Won
Min, Kil Sik
trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)
title trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)
title_full trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)
title_fullStr trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)
title_full_unstemmed trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)
title_short trans-Diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(II)
title_sort trans-diazido­(1,8-dibenzyl-1,3,6,8,10,13-hexa­azacyclo­tetra­deca­ne)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961652/
https://www.ncbi.nlm.nih.gov/pubmed/21202794
http://dx.doi.org/10.1107/S1600536808018199
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AT minkilsik transdiazido18dibenzyl13681013hexaazacyclotetradecanenickelii

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