Hexaaqua­magnesium(II) bis­(d-camphor-10-sulfonate)

The structure of the title complex, [Mg(H(2)O)(6)](C(10)H(15)O(4)S)(2), consists of regular octa­hedral [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. A three-dimensional supra­molecular architecture is formed via hydrogen-bond inter­actions [O—H⋯O = 2.723 (2)–2.833 (2) Å] to give alt...

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Detalles Bibliográficos
Autores principales: Jeremić, Dejan, Kaluderović, Goran N., Brčeski, Ilija, Gómez-Ruiz, Santiago, Andelković, Katarina K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961654/
https://www.ncbi.nlm.nih.gov/pubmed/21202801
http://dx.doi.org/10.1107/S1600536808018047
Descripción
Sumario:The structure of the title complex, [Mg(H(2)O)(6)](C(10)H(15)O(4)S)(2), consists of regular octa­hedral [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. A three-dimensional supra­molecular architecture is formed via hydrogen-bond inter­actions [O—H⋯O = 2.723 (2)–2.833 (2) Å] to give alternating layers of [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. The title compound is isomorphous with the zinc, copper, cadmium and nickel analogues.

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