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2-Amino-N-(2-benzyloxy-3-methoxybenzylidene)aniline
The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent molecules (A and B) in the asymmetric unit, with similar conformations. In molecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzen...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961660/ https://www.ncbi.nlm.nih.gov/pubmed/21202921 http://dx.doi.org/10.1107/S1600536808017844 |
Sumario: | The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent molecules (A and B) in the asymmetric unit, with similar conformations. In molecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzene rings, while in molecule B these angles are 32.30 (13) and 13.13 (12)°. The molecular structure is stabilized by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure is stabilized by N—H⋯N hydrogen bonds and N—H⋯π and C—H⋯π interactions. |
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