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2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline

The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol­ecules (A and B) in the asymmetric unit, with similar conformations. In mol­ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzen...

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Detalles Bibliográficos
Autores principales: Al-Douh, Mohammed H., Hamid, Shafida A., Osman, Hasnah, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961660/
https://www.ncbi.nlm.nih.gov/pubmed/21202921
http://dx.doi.org/10.1107/S1600536808017844
Descripción
Sumario:The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol­ecules (A and B) in the asymmetric unit, with similar conformations. In mol­ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzene rings, while in mol­ecule B these angles are 32.30 (13) and 13.13 (12)°. The mol­ecular structure is stabilized by intra­molecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure is stabilized by N—H⋯N hydrogen bonds and N—H⋯π and C—H⋯π inter­actions.