2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline

The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol­ecules (A and B) in the asymmetric unit, with similar conformations. In mol­ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzen...

Descripción completa

Detalles Bibliográficos
Autores principales: Al-Douh, Mohammed H., Hamid, Shafida A., Osman, Hasnah, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961660/
https://www.ncbi.nlm.nih.gov/pubmed/21202921
http://dx.doi.org/10.1107/S1600536808017844
_version_ 1782189035575312384
author Al-Douh, Mohammed H.
Hamid, Shafida A.
Osman, Hasnah
Kia, Reza
Fun, Hoong-Kun
author_facet Al-Douh, Mohammed H.
Hamid, Shafida A.
Osman, Hasnah
Kia, Reza
Fun, Hoong-Kun
author_sort Al-Douh, Mohammed H.
collection PubMed
description The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol­ecules (A and B) in the asymmetric unit, with similar conformations. In mol­ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzene rings, while in mol­ecule B these angles are 32.30 (13) and 13.13 (12)°. The mol­ecular structure is stabilized by intra­molecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure is stabilized by N—H⋯N hydrogen bonds and N—H⋯π and C—H⋯π inter­actions.
format Text
id pubmed-2961660
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29616602010-12-30 2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline Al-Douh, Mohammed H. Hamid, Shafida A. Osman, Hasnah Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol­ecules (A and B) in the asymmetric unit, with similar conformations. In mol­ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzene rings, while in mol­ecule B these angles are 32.30 (13) and 13.13 (12)°. The mol­ecular structure is stabilized by intra­molecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure is stabilized by N—H⋯N hydrogen bonds and N—H⋯π and C—H⋯π inter­actions. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961660/ /pubmed/21202921 http://dx.doi.org/10.1107/S1600536808017844 Text en © Al-Douh et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Douh, Mohammed H.
Hamid, Shafida A.
Osman, Hasnah
Kia, Reza
Fun, Hoong-Kun
2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
title 2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
title_full 2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
title_fullStr 2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
title_full_unstemmed 2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
title_short 2-Amino-N-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
title_sort 2-amino-n-(2-benz­yloxy-3-methoxy­benzyl­idene)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961660/
https://www.ncbi.nlm.nih.gov/pubmed/21202921
http://dx.doi.org/10.1107/S1600536808017844
work_keys_str_mv AT aldouhmohammedh 2aminon2benzyloxy3methoxybenzylideneaniline
AT hamidshafidaa 2aminon2benzyloxy3methoxybenzylideneaniline
AT osmanhasnah 2aminon2benzyloxy3methoxybenzylideneaniline
AT kiareza 2aminon2benzyloxy3methoxybenzylideneaniline
AT funhoongkun 2aminon2benzyloxy3methoxybenzylideneaniline

Ejemplares similares