Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)

The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N′-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe—N(amino) bond is longer than the Fe—N(anilide) bond by about 0.37 Å. The mol­ecule disp...

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Detalles Bibliográficos
Autor principal: Chen, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961661/
https://www.ncbi.nlm.nih.gov/pubmed/21202791
http://dx.doi.org/10.1107/S1600536808018114
Descripción
Sumario:The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N′-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe—N(amino) bond is longer than the Fe—N(anilide) bond by about 0.37 Å. The mol­ecule displays a pseudo-twofold rotation. The five–coordinate Fe atom demonstrates a highly distorted trigonal–bipyramidal geometry.

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