Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)

The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N′-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe—N(amino) bond is longer than the Fe—N(anilide) bond by about 0.37 Å. The mol­ecule disp...

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Detalles Bibliográficos
Autor principal: Chen, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961661/
https://www.ncbi.nlm.nih.gov/pubmed/21202791
http://dx.doi.org/10.1107/S1600536808018114
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author Chen, Juan
author_facet Chen, Juan
author_sort Chen, Juan
collection PubMed
description The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N′-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe—N(amino) bond is longer than the Fe—N(anilide) bond by about 0.37 Å. The mol­ecule displays a pseudo-twofold rotation. The five–coordinate Fe atom demonstrates a highly distorted trigonal–bipyramidal geometry.
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spelling pubmed-29616612010-12-30 Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III) Chen, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N′-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe—N(amino) bond is longer than the Fe—N(anilide) bond by about 0.37 Å. The mol­ecule displays a pseudo-twofold rotation. The five–coordinate Fe atom demonstrates a highly distorted trigonal–bipyramidal geometry. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961661/ /pubmed/21202791 http://dx.doi.org/10.1107/S1600536808018114 Text en © Juan Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Juan
Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)
title Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)
title_full Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)
title_fullStr Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)
title_full_unstemmed Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)
title_short Chloridobis{N-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) N,N′}iron(III)
title_sort chloridobis{n-[(dimethyl­amino)dimethyl­silyl]-2,6-dimethyl­anilido-κ(2) n,n′}iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961661/
https://www.ncbi.nlm.nih.gov/pubmed/21202791
http://dx.doi.org/10.1107/S1600536808018114
work_keys_str_mv AT chenjuan chloridobisndimethylaminodimethylsilyl26dimethylanilidok2nnironiii

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