catena-Poly[[bis­(methanol-κO)bis­(pyridine-κN)nickel(II)]-μ-tetra­fluoro­terephthalato-κ(2) O:O′]

In the title compound, [Ni(C(8)F(4)O(4))(C(5)H(5)N)(2)(CH(4)O)(2)](n), the Ni(II) ion is located on an inversion center and is coordinated by four O atoms [Ni—O = 2.079 (4) Å] from two tetra­fluoro­terephthalate ligands and two methanol mol­ecules, and by two N atoms [Ni—N = 2.127 (4) Å] from two py...

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Detalles Bibliográficos
Autores principales: Zheng, Chang-Ge, Hong, Jian-Quan, Zhang, Jie, Wang, Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961662/
https://www.ncbi.nlm.nih.gov/pubmed/21202750
http://dx.doi.org/10.1107/S1600536808016619
Descripción
Sumario:In the title compound, [Ni(C(8)F(4)O(4))(C(5)H(5)N)(2)(CH(4)O)(2)](n), the Ni(II) ion is located on an inversion center and is coordinated by four O atoms [Ni—O = 2.079 (4) Å] from two tetra­fluoro­terephthalate ligands and two methanol mol­ecules, and by two N atoms [Ni—N = 2.127 (4) Å] from two pyridine ligands in a distorted octa­hedral geometry. The Ni(II) ions are connected via the tetra­fluoro­terephthalate anions into a one-dimensional chain running along the crystallographic [011] direction.

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