Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]

The asymmetric unit of the title complex, [Cu(2)(CN)(2)(C(20)H(16)N(6)S(2))](n), contains one Cu(I) cation, one cyanide ligand and half of a centrosymmetric 1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane (bppe) ligand. The Cu(I) atom displays a trigonal coordination geometry, being surrounded...

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Detalles Bibliográficos
Autores principales: Zhang, Ya-Wen, Dong, Hua-Ze, Cheng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961664/
https://www.ncbi.nlm.nih.gov/pubmed/21202742
http://dx.doi.org/10.1107/S1600536808013172
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author Zhang, Ya-Wen
Dong, Hua-Ze
Cheng, Lin
author_facet Zhang, Ya-Wen
Dong, Hua-Ze
Cheng, Lin
author_sort Zhang, Ya-Wen
collection PubMed
description The asymmetric unit of the title complex, [Cu(2)(CN)(2)(C(20)H(16)N(6)S(2))](n), contains one Cu(I) cation, one cyanide ligand and half of a centrosymmetric 1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane (bppe) ligand. The Cu(I) atom displays a trigonal coordination geometry, being surrounded by one C atom from one cyanide anion and two N atoms from one cyanide and one bppe ligand. In the complex, each cyanide anion links two Cu(I) atoms in a bis-monodentate mode into a zigzag [–Cu—CN–](n) chain. Two parallel chains are linked by bppe ligands into a ladder chain.
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spelling pubmed-29616642010-12-30 Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)] Zhang, Ya-Wen Dong, Hua-Ze Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Cu(2)(CN)(2)(C(20)H(16)N(6)S(2))](n), contains one Cu(I) cation, one cyanide ligand and half of a centrosymmetric 1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane (bppe) ligand. The Cu(I) atom displays a trigonal coordination geometry, being surrounded by one C atom from one cyanide anion and two N atoms from one cyanide and one bppe ligand. In the complex, each cyanide anion links two Cu(I) atoms in a bis-monodentate mode into a zigzag [–Cu—CN–](n) chain. Two parallel chains are linked by bppe ligands into a ladder chain. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961664/ /pubmed/21202742 http://dx.doi.org/10.1107/S1600536808013172 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Ya-Wen
Dong, Hua-Ze
Cheng, Lin
Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]
title Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]
title_full Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]
title_fullStr Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]
title_full_unstemmed Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]
title_short Poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(I)]
title_sort poly[{μ(2)-1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane}di-μ(2)-cyanido-dicopper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961664/
https://www.ncbi.nlm.nih.gov/pubmed/21202742
http://dx.doi.org/10.1107/S1600536808013172
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AT chenglin polym212bis43pyridylpyrimidin2ylsulfanylethanedim2cyanidodicopperi

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