1,4-Bis(4-pyridylsulfanylmeth­yl)benzene

In the title compound, C(18)H(16)N(2)S(2), a crystallographic inversion centre lies at the centre of the benzene ring, and the two terminal 4-mercaptopyridyl groups adopt an anti geometry. Each benzene ring makes a dihedral angle of 55.4 (1)° with the plane of the benzene fragment. The crystal struc...

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Detalles Bibliográficos
Autores principales: Moon, Suk-Hee, Park, Ki-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961669/
https://www.ncbi.nlm.nih.gov/pubmed/21202916
http://dx.doi.org/10.1107/S1600536808017571
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author Moon, Suk-Hee
Park, Ki-Min
author_facet Moon, Suk-Hee
Park, Ki-Min
author_sort Moon, Suk-Hee
collection PubMed
description In the title compound, C(18)H(16)N(2)S(2), a crystallographic inversion centre lies at the centre of the benzene ring, and the two terminal 4-mercaptopyridyl groups adopt an anti geometry. Each benzene ring makes a dihedral angle of 55.4 (1)° with the plane of the benzene fragment. The crystal structure is stabilized by C—H⋯π inter­actions between a benzene H atom and a pyridyl ring of a neighbouring mol­ecule. In addition, the crystal structure exhibits inter­molecular C—H⋯N inter­actions.
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spelling pubmed-29616692010-12-30 1,4-Bis(4-pyridylsulfanylmeth­yl)benzene Moon, Suk-Hee Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)N(2)S(2), a crystallographic inversion centre lies at the centre of the benzene ring, and the two terminal 4-mercaptopyridyl groups adopt an anti geometry. Each benzene ring makes a dihedral angle of 55.4 (1)° with the plane of the benzene fragment. The crystal structure is stabilized by C—H⋯π inter­actions between a benzene H atom and a pyridyl ring of a neighbouring mol­ecule. In addition, the crystal structure exhibits inter­molecular C—H⋯N inter­actions. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961669/ /pubmed/21202916 http://dx.doi.org/10.1107/S1600536808017571 Text en © Moon and Park 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moon, Suk-Hee
Park, Ki-Min
1,4-Bis(4-pyridylsulfanylmeth­yl)benzene
title 1,4-Bis(4-pyridylsulfanylmeth­yl)benzene
title_full 1,4-Bis(4-pyridylsulfanylmeth­yl)benzene
title_fullStr 1,4-Bis(4-pyridylsulfanylmeth­yl)benzene
title_full_unstemmed 1,4-Bis(4-pyridylsulfanylmeth­yl)benzene
title_short 1,4-Bis(4-pyridylsulfanylmeth­yl)benzene
title_sort 1,4-bis(4-pyridylsulfanylmeth­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961669/
https://www.ncbi.nlm.nih.gov/pubmed/21202916
http://dx.doi.org/10.1107/S1600536808017571
work_keys_str_mv AT moonsukhee 14bis4pyridylsulfanylmethylbenzene
AT parkkimin 14bis4pyridylsulfanylmethylbenzene

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