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4-(Dimethylamino)benzaldehyde
The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical molecules in the asymmetric unit, which are linked via a C—H⋯π interaction. In both molecules, the aldehyde and dimethylamine groups are essentially coplanar with the attached benzene ring. In the crysta...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961670/ https://www.ncbi.nlm.nih.gov/pubmed/21202825 http://dx.doi.org/10.1107/S160053680801581X |
Sumario: | The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical molecules in the asymmetric unit, which are linked via a C—H⋯π interaction. In both molecules, the aldehyde and dimethylamine groups are essentially coplanar with the attached benzene ring. In the crystal structure, C—H⋯O hydrogen bonds link one type of independent molecules into a chain along the a axis. In addition, the structure is stabilized by π–π stacking interactions involving the benzene rings [centroid-to-centroid distance = 3.697 (2) Å]. |
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