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4-(Dimethyl­amino)benzaldehyde

The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical mol­ecules in the asymmetric unit, which are linked via a C—H⋯π inter­action. In both mol­ecules, the aldehyde and dimethyl­amine groups are essentially coplanar with the attached benzene ring. In the crysta...

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Detalles Bibliográficos
Autores principales: Gao, Bo, Zhu, Jian-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961670/
https://www.ncbi.nlm.nih.gov/pubmed/21202825
http://dx.doi.org/10.1107/S160053680801581X
Descripción
Sumario:The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical mol­ecules in the asymmetric unit, which are linked via a C—H⋯π inter­action. In both mol­ecules, the aldehyde and dimethyl­amine groups are essentially coplanar with the attached benzene ring. In the crystal structure, C—H⋯O hydrogen bonds link one type of independent mol­ecules into a chain along the a axis. In addition, the structure is stabilized by π–π stacking inter­actions involving the benzene rings [centroid-to-centroid distance = 3.697 (2) Å].