4-(Dimethyl­amino)benzaldehyde

The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical mol­ecules in the asymmetric unit, which are linked via a C—H⋯π inter­action. In both mol­ecules, the aldehyde and dimethyl­amine groups are essentially coplanar with the attached benzene ring. In the crysta...

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Detalles Bibliográficos
Autores principales: Gao, Bo, Zhu, Jian-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961670/
https://www.ncbi.nlm.nih.gov/pubmed/21202825
http://dx.doi.org/10.1107/S160053680801581X
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author Gao, Bo
Zhu, Jian-Liang
author_facet Gao, Bo
Zhu, Jian-Liang
author_sort Gao, Bo
collection PubMed
description The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical mol­ecules in the asymmetric unit, which are linked via a C—H⋯π inter­action. In both mol­ecules, the aldehyde and dimethyl­amine groups are essentially coplanar with the attached benzene ring. In the crystal structure, C—H⋯O hydrogen bonds link one type of independent mol­ecules into a chain along the a axis. In addition, the structure is stabilized by π–π stacking inter­actions involving the benzene rings [centroid-to-centroid distance = 3.697 (2) Å].
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spelling pubmed-29616702010-12-30 4-(Dimethyl­amino)benzaldehyde Gao, Bo Zhu, Jian-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(11)NO, crystallizes with two independent but essentially identical mol­ecules in the asymmetric unit, which are linked via a C—H⋯π inter­action. In both mol­ecules, the aldehyde and dimethyl­amine groups are essentially coplanar with the attached benzene ring. In the crystal structure, C—H⋯O hydrogen bonds link one type of independent mol­ecules into a chain along the a axis. In addition, the structure is stabilized by π–π stacking inter­actions involving the benzene rings [centroid-to-centroid distance = 3.697 (2) Å]. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961670/ /pubmed/21202825 http://dx.doi.org/10.1107/S160053680801581X Text en © Gao and Zhu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Bo
Zhu, Jian-Liang
4-(Dimethyl­amino)benzaldehyde
title 4-(Dimethyl­amino)benzaldehyde
title_full 4-(Dimethyl­amino)benzaldehyde
title_fullStr 4-(Dimethyl­amino)benzaldehyde
title_full_unstemmed 4-(Dimethyl­amino)benzaldehyde
title_short 4-(Dimethyl­amino)benzaldehyde
title_sort 4-(dimethyl­amino)benzaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961670/
https://www.ncbi.nlm.nih.gov/pubmed/21202825
http://dx.doi.org/10.1107/S160053680801581X
work_keys_str_mv AT gaobo 4dimethylaminobenzaldehyde
AT zhujianliang 4dimethylaminobenzaldehyde

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