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Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate

In the crystal structure of the title compound, [Cd(C(7)H(5)O(4))(2)(C(12)H(8)N(2))(2)]·1.25H(2)O, the Cd(2+) cation is coordinated by two phenanthroline (phen) mol­ecules and two 2,5-dihydroxy­benzoate (dhba) anions in a distorted octa­hedral geometry. The centroid–centroid distances of 3.809 (2) a...

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Detalles Bibliográficos
Autores principales: Zhang, Bing-Yu, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961672/
https://www.ncbi.nlm.nih.gov/pubmed/21202790
http://dx.doi.org/10.1107/S1600536808018126
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author Zhang, Bing-Yu
Nie, Jing-Jing
Xu, Duan-Jun
author_facet Zhang, Bing-Yu
Nie, Jing-Jing
Xu, Duan-Jun
author_sort Zhang, Bing-Yu
collection PubMed
description In the crystal structure of the title compound, [Cd(C(7)H(5)O(4))(2)(C(12)H(8)N(2))(2)]·1.25H(2)O, the Cd(2+) cation is coordinated by two phenanthroline (phen) mol­ecules and two 2,5-dihydroxy­benzoate (dhba) anions in a distorted octa­hedral geometry. The centroid–centroid distances of 3.809 (2) and 3.680 (2) Å between nearly parallel pyridine rings of the phen ligands and the benzene rings of dhba anions indicate that the dhba anions are involved in π–π stacking in the crystal structure. The face-to-face separation of 3.35 (3) Å between parallel phen ring systems also suggests π–π stacking between adjacent complex mol­ecules. The crystal structure contains extensive O—H⋯O and C—H⋯O hydrogen bonding.
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spelling pubmed-29616722010-12-30 Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cd(C(7)H(5)O(4))(2)(C(12)H(8)N(2))(2)]·1.25H(2)O, the Cd(2+) cation is coordinated by two phenanthroline (phen) mol­ecules and two 2,5-dihydroxy­benzoate (dhba) anions in a distorted octa­hedral geometry. The centroid–centroid distances of 3.809 (2) and 3.680 (2) Å between nearly parallel pyridine rings of the phen ligands and the benzene rings of dhba anions indicate that the dhba anions are involved in π–π stacking in the crystal structure. The face-to-face separation of 3.35 (3) Å between parallel phen ring systems also suggests π–π stacking between adjacent complex mol­ecules. The crystal structure contains extensive O—H⋯O and C—H⋯O hydrogen bonding. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961672/ /pubmed/21202790 http://dx.doi.org/10.1107/S1600536808018126 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Bing-Yu
Nie, Jing-Jing
Xu, Duan-Jun
Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
title Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
title_full Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
title_fullStr Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
title_full_unstemmed Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
title_short Bis(2,5-dihydroxy­benzoato-κO)bis­(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
title_sort bis(2,5-dihydroxy­benzoato-κo)bis­(1,10-phenathroline-κ(2) n,n′)cadmium(ii) 1.25-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961672/
https://www.ncbi.nlm.nih.gov/pubmed/21202790
http://dx.doi.org/10.1107/S1600536808018126
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