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Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate
In the crystal structure of the title compound, [Cd(C(7)H(5)O(4))(2)(C(12)H(8)N(2))(2)]·1.25H(2)O, the Cd(2+) cation is coordinated by two phenanthroline (phen) molecules and two 2,5-dihydroxybenzoate (dhba) anions in a distorted octahedral geometry. The centroid–centroid distances of 3.809 (2) a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961672/ https://www.ncbi.nlm.nih.gov/pubmed/21202790 http://dx.doi.org/10.1107/S1600536808018126 |
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author | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
author_facet | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
author_sort | Zhang, Bing-Yu |
collection | PubMed |
description | In the crystal structure of the title compound, [Cd(C(7)H(5)O(4))(2)(C(12)H(8)N(2))(2)]·1.25H(2)O, the Cd(2+) cation is coordinated by two phenanthroline (phen) molecules and two 2,5-dihydroxybenzoate (dhba) anions in a distorted octahedral geometry. The centroid–centroid distances of 3.809 (2) and 3.680 (2) Å between nearly parallel pyridine rings of the phen ligands and the benzene rings of dhba anions indicate that the dhba anions are involved in π–π stacking in the crystal structure. The face-to-face separation of 3.35 (3) Å between parallel phen ring systems also suggests π–π stacking between adjacent complex molecules. The crystal structure contains extensive O—H⋯O and C—H⋯O hydrogen bonding. |
format | Text |
id | pubmed-2961672 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616722010-12-30 Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cd(C(7)H(5)O(4))(2)(C(12)H(8)N(2))(2)]·1.25H(2)O, the Cd(2+) cation is coordinated by two phenanthroline (phen) molecules and two 2,5-dihydroxybenzoate (dhba) anions in a distorted octahedral geometry. The centroid–centroid distances of 3.809 (2) and 3.680 (2) Å between nearly parallel pyridine rings of the phen ligands and the benzene rings of dhba anions indicate that the dhba anions are involved in π–π stacking in the crystal structure. The face-to-face separation of 3.35 (3) Å between parallel phen ring systems also suggests π–π stacking between adjacent complex molecules. The crystal structure contains extensive O—H⋯O and C—H⋯O hydrogen bonding. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961672/ /pubmed/21202790 http://dx.doi.org/10.1107/S1600536808018126 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2) N,N′)cadmium(II) 1.25-hydrate |
title | Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2)
N,N′)cadmium(II) 1.25-hydrate |
title_full | Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2)
N,N′)cadmium(II) 1.25-hydrate |
title_fullStr | Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2)
N,N′)cadmium(II) 1.25-hydrate |
title_full_unstemmed | Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2)
N,N′)cadmium(II) 1.25-hydrate |
title_short | Bis(2,5-dihydroxybenzoato-κO)bis(1,10-phenathroline-κ(2)
N,N′)cadmium(II) 1.25-hydrate |
title_sort | bis(2,5-dihydroxybenzoato-κo)bis(1,10-phenathroline-κ(2)
n,n′)cadmium(ii) 1.25-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961672/ https://www.ncbi.nlm.nih.gov/pubmed/21202790 http://dx.doi.org/10.1107/S1600536808018126 |
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