catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]

The title compound, [CuBr(C(9)H(9)N(5))](n), prepared by the solvothermal treatment of CuBr with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine, is a new homometallic Cu(I)–olefin coordination polymer in which dinuclear Cu(2)Br(2) units are linked by the organic olefin ligand 4-(2-allyl-2H-tetra­zol-5-yl)pyr...

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Detalles Bibliográficos
Autor principal: Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961675/
https://www.ncbi.nlm.nih.gov/pubmed/21202766
http://dx.doi.org/10.1107/S1600536808012439
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author Wang, Wei
author_facet Wang, Wei
author_sort Wang, Wei
collection PubMed
description The title compound, [CuBr(C(9)H(9)N(5))](n), prepared by the solvothermal treatment of CuBr with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine, is a new homometallic Cu(I)–olefin coordination polymer in which dinuclear Cu(2)Br(2) units are linked by the organic olefin ligand 4-(2-allyl-2H-tetra­zol-5-yl)pyridine, which acts as a bidentate ligand connecting two neighbouring Cu(2)Br(2) units through the pyridine N atom and the double bond of the allyl group. The coordination of Cu(I) is slightly distorted tetrahedral.
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spelling pubmed-29616752010-12-30 catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]] Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuBr(C(9)H(9)N(5))](n), prepared by the solvothermal treatment of CuBr with 4-(2-allyl-2H-tetra­zol-5-yl)pyridine, is a new homometallic Cu(I)–olefin coordination polymer in which dinuclear Cu(2)Br(2) units are linked by the organic olefin ligand 4-(2-allyl-2H-tetra­zol-5-yl)pyridine, which acts as a bidentate ligand connecting two neighbouring Cu(2)Br(2) units through the pyridine N atom and the double bond of the allyl group. The coordination of Cu(I) is slightly distorted tetrahedral. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961675/ /pubmed/21202766 http://dx.doi.org/10.1107/S1600536808012439 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_full catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_fullStr catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_full_unstemmed catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_short catena-Poly[[di-μ-bromido-dicopper(I)]bis­[μ-η(2),σ(1)-4-(2-allyl-2H-tetra­zol-5-yl)pyridine]]
title_sort catena-poly[[di-μ-bromido-dicopper(i)]bis­[μ-η(2),σ(1)-4-(2-allyl-2h-tetra­zol-5-yl)pyridine]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961675/
https://www.ncbi.nlm.nih.gov/pubmed/21202766
http://dx.doi.org/10.1107/S1600536808012439
work_keys_str_mv AT wangwei catenapolydimbromidodicopperibismē2s142allyl2htetrazol5ylpyridine

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