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LiDy(PO(3))(4)
Single crystals of lithium dysprosium polyphosphate, LiDy(PO(3))(4), were prepared by the flux method. The atomic arrangement is built up by infinite (PO(3))(n) chains extending along the b axis. Dy(3+) and Li(+) cations alternate in the middle of four such chains, with Dy⋯Li distances of 3.54 (1) a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961678/ https://www.ncbi.nlm.nih.gov/pubmed/21202729 http://dx.doi.org/10.1107/S1600536808016875 |
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author | Chehimi-Moumen, Fathia Férid, Mokhtar |
author_facet | Chehimi-Moumen, Fathia Férid, Mokhtar |
author_sort | Chehimi-Moumen, Fathia |
collection | PubMed |
description | Single crystals of lithium dysprosium polyphosphate, LiDy(PO(3))(4), were prepared by the flux method. The atomic arrangement is built up by infinite (PO(3))(n) chains extending along the b axis. Dy(3+) and Li(+) cations alternate in the middle of four such chains, with Dy⋯Li distances of 3.54 (1) and 3.48 (1) Å. The DyO(8) dodecahedra and LiO(4) tetrahedra deviate significantly from the ideal geometry. Both Dy and Li occupy special positions (Wyckoff position 4e, site symmetry 2). |
format | Text |
id | pubmed-2961678 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616782010-12-30 LiDy(PO(3))(4) Chehimi-Moumen, Fathia Férid, Mokhtar Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of lithium dysprosium polyphosphate, LiDy(PO(3))(4), were prepared by the flux method. The atomic arrangement is built up by infinite (PO(3))(n) chains extending along the b axis. Dy(3+) and Li(+) cations alternate in the middle of four such chains, with Dy⋯Li distances of 3.54 (1) and 3.48 (1) Å. The DyO(8) dodecahedra and LiO(4) tetrahedra deviate significantly from the ideal geometry. Both Dy and Li occupy special positions (Wyckoff position 4e, site symmetry 2). International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961678/ /pubmed/21202729 http://dx.doi.org/10.1107/S1600536808016875 Text en © Chehimi-Moumen and Mokhtar 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Chehimi-Moumen, Fathia Férid, Mokhtar LiDy(PO(3))(4) |
title | LiDy(PO(3))(4)
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title_full | LiDy(PO(3))(4)
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title_fullStr | LiDy(PO(3))(4)
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title_full_unstemmed | LiDy(PO(3))(4)
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title_short | LiDy(PO(3))(4)
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title_sort | lidy(po(3))(4) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961678/ https://www.ncbi.nlm.nih.gov/pubmed/21202729 http://dx.doi.org/10.1107/S1600536808016875 |
work_keys_str_mv | AT chehimimoumenfathia lidypo34 AT feridmokhtar lidypo34 |