Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]

The title polymeric compound, [Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2)](n), was obtained by the reaction of manganese(II) chloride tetra­hydrate with benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa­hedral geometry by two N atoms...

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Detalles Bibliográficos
Autores principales: Jiang, Xin-Dong, Li, Xiu-Bing, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961681/
https://www.ncbi.nlm.nih.gov/pubmed/21202779
http://dx.doi.org/10.1107/S1600536808016723
Descripción
Sumario:The title polymeric compound, [Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2)](n), was obtained by the reaction of manganese(II) chloride tetra­hydrate with benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa­hedral geometry by two N atoms from one 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.116 (2)–2.237 (2) Å] from three bta(4−) ligands, which also act as bridging groups between the Mn(2+) ions.

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