Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]

The title polymeric compound, [Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2)](n), was obtained by the reaction of manganese(II) chloride tetra­hydrate with benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa­hedral geometry by two N atoms...

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Detalles Bibliográficos
Autores principales: Jiang, Xin-Dong, Li, Xiu-Bing, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961681/
https://www.ncbi.nlm.nih.gov/pubmed/21202779
http://dx.doi.org/10.1107/S1600536808016723
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author Jiang, Xin-Dong
Li, Xiu-Bing
Sun, Bai-Wang
author_facet Jiang, Xin-Dong
Li, Xiu-Bing
Sun, Bai-Wang
author_sort Jiang, Xin-Dong
collection PubMed
description The title polymeric compound, [Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2)](n), was obtained by the reaction of manganese(II) chloride tetra­hydrate with benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa­hedral geometry by two N atoms from one 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.116 (2)–2.237 (2) Å] from three bta(4−) ligands, which also act as bridging groups between the Mn(2+) ions.
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spelling pubmed-29616812010-12-30 Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)] Jiang, Xin-Dong Li, Xiu-Bing Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymeric compound, [Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2)](n), was obtained by the reaction of manganese(II) chloride tetra­hydrate with benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa­hedral geometry by two N atoms from one 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.116 (2)–2.237 (2) Å] from three bta(4−) ligands, which also act as bridging groups between the Mn(2+) ions. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961681/ /pubmed/21202779 http://dx.doi.org/10.1107/S1600536808016723 Text en © Jiang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Xin-Dong
Li, Xiu-Bing
Sun, Bai-Wang
Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]
title Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]
title_full Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]
title_fullStr Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]
title_full_unstemmed Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]
title_short Poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) N,N′)dimanganese(II)]
title_sort poly[(μ (6)-benzene-1,2,4,5-tetra­carboxyl­ato)bis­(1,10-phenanthroline-κ (2) n,n′)dimanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961681/
https://www.ncbi.nlm.nih.gov/pubmed/21202779
http://dx.doi.org/10.1107/S1600536808016723
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