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Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate

In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octa­hedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent...

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Detalles Bibliográficos
Autores principales: Ding, Yu, Li, Chunlian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961690/
https://www.ncbi.nlm.nih.gov/pubmed/21202814
http://dx.doi.org/10.1107/S1600536808018989
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author Ding, Yu
Li, Chunlian
author_facet Ding, Yu
Li, Chunlian
author_sort Ding, Yu
collection PubMed
description In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octa­hedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds into one-dimensional chains along [010]. In addition, the crystal structure is stabilized by weak C—H⋯O and C—H⋯N hydrogen bonds.
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spelling pubmed-29616902010-12-30 Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate Ding, Yu Li, Chunlian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octa­hedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds into one-dimensional chains along [010]. In addition, the crystal structure is stabilized by weak C—H⋯O and C—H⋯N hydrogen bonds. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961690/ /pubmed/21202814 http://dx.doi.org/10.1107/S1600536808018989 Text en © Yu Ding 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, Yu
Li, Chunlian
Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate
title Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate
title_full Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate
title_fullStr Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate
title_full_unstemmed Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate
title_short Hexakis(1H-imidazole-κN (3))nickel(II) bis­(2,4-dibromo-6-formyl­phenolate) N,N-dimethyl­formamide disolvate
title_sort hexakis(1h-imidazole-κn (3))nickel(ii) bis­(2,4-dibromo-6-formyl­phenolate) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961690/
https://www.ncbi.nlm.nih.gov/pubmed/21202814
http://dx.doi.org/10.1107/S1600536808018989
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