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Hexakis(1H-imidazole-κN (3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate
In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octahedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961690/ https://www.ncbi.nlm.nih.gov/pubmed/21202814 http://dx.doi.org/10.1107/S1600536808018989 |
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author | Ding, Yu Li, Chunlian |
author_facet | Ding, Yu Li, Chunlian |
author_sort | Ding, Yu |
collection | PubMed |
description | In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octahedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent molecules are linked by intermolecular N—H⋯O hydrogen bonds into one-dimensional chains along [010]. In addition, the crystal structure is stabilized by weak C—H⋯O and C—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2961690 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616902010-12-30 Hexakis(1H-imidazole-κN (3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate Ding, Yu Li, Chunlian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octahedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent molecules are linked by intermolecular N—H⋯O hydrogen bonds into one-dimensional chains along [010]. In addition, the crystal structure is stabilized by weak C—H⋯O and C—H⋯N hydrogen bonds. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961690/ /pubmed/21202814 http://dx.doi.org/10.1107/S1600536808018989 Text en © Yu Ding 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ding, Yu Li, Chunlian Hexakis(1H-imidazole-κN (3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate |
title | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate |
title_full | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate |
title_fullStr | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate |
title_full_unstemmed | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate |
title_short | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(2,4-dibromo-6-formylphenolate) N,N-dimethylformamide disolvate |
title_sort | hexakis(1h-imidazole-κn
(3))nickel(ii) bis(2,4-dibromo-6-formylphenolate) n,n-dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961690/ https://www.ncbi.nlm.nih.gov/pubmed/21202814 http://dx.doi.org/10.1107/S1600536808018989 |
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