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catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine]
The title compound, [CuCl(C(9)H(9)N(5))](n), prepared by solvothermal synthesis, is a new homometallic Cu(I)–olefin coordination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetrazol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom. The organic ligand acts as a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961697/ https://www.ncbi.nlm.nih.gov/pubmed/21202765 http://dx.doi.org/10.1107/S1600536808013895 |
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author | Wang, Wei |
author_facet | Wang, Wei |
author_sort | Wang, Wei |
collection | PubMed |
description | The title compound, [CuCl(C(9)H(9)N(5))](n), prepared by solvothermal synthesis, is a new homometallic Cu(I)–olefin coordination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetrazol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom. The organic ligand acts as a bidentate ligand bridging two neighboring Cu centers through the bonds to the N atom of the pyridine ring and the double bond of the allyl group. Weak Cu⋯Cl [3.136 (8) Å), C—H⋯Cl and C—H⋯N interactions connect the coordination polymers into a three-dimensional structure. |
format | Text |
id | pubmed-2961697 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29616972010-12-30 catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuCl(C(9)H(9)N(5))](n), prepared by solvothermal synthesis, is a new homometallic Cu(I)–olefin coordination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetrazol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom. The organic ligand acts as a bidentate ligand bridging two neighboring Cu centers through the bonds to the N atom of the pyridine ring and the double bond of the allyl group. Weak Cu⋯Cl [3.136 (8) Å), C—H⋯Cl and C—H⋯N interactions connect the coordination polymers into a three-dimensional structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961697/ /pubmed/21202765 http://dx.doi.org/10.1107/S1600536808013895 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Wei catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] |
title |
catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] |
title_full |
catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] |
title_fullStr |
catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] |
title_full_unstemmed |
catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] |
title_short |
catena-Poly[[chloridocopper(I)]-μ-η(2),σ(1)-3-(2-allyl-2H-tetrazol-5-yl)pyridine] |
title_sort | catena-poly[[chloridocopper(i)]-μ-η(2),σ(1)-3-(2-allyl-2h-tetrazol-5-yl)pyridine] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961697/ https://www.ncbi.nlm.nih.gov/pubmed/21202765 http://dx.doi.org/10.1107/S1600536808013895 |
work_keys_str_mv | AT wangwei catenapolychloridocopperimē2s132allyl2htetrazol5ylpyridine |