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Diaquabis[2-(benzyloxy)acetato]cobalt(II)
In the mononuclear title complex, [Co(C(9)H(9)O(3))(2)(H(2)O)(2)], each Co(II) atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co—O bond lengths = 2.0487 (9) and 2.1090 (9) Å] and two water molecules [Co—O bond length = 2.0873 (9) Å...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961700/ https://www.ncbi.nlm.nih.gov/pubmed/21202757 http://dx.doi.org/10.1107/S1600536808016899 |
| _version_ | 1782189045111062528 |
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| author | Chen, Chun-Liang Sun, Sheng-Li Gu, Chang-Sheng Song, Weng-Dong Hao, Xiao-Min |
| author_facet | Chen, Chun-Liang Sun, Sheng-Li Gu, Chang-Sheng Song, Weng-Dong Hao, Xiao-Min |
| author_sort | Chen, Chun-Liang |
| collection | PubMed |
| description | In the mononuclear title complex, [Co(C(9)H(9)O(3))(2)(H(2)O)(2)], each Co(II) atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co—O bond lengths = 2.0487 (9) and 2.1090 (9) Å] and two water molecules [Co—O bond length = 2.0873 (9) Å] in a distorted octahedral geometry. In the crystal structure, intermolecular hydrogen bonds and π–π stacking interactions [centroid–centroid distance between phenyl rings = 3.692 (2) Å] link the molecules into a supramolecular structure. |
| format | Text |
| id | pubmed-2961700 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29617002010-12-30 Diaquabis[2-(benzyloxy)acetato]cobalt(II) Chen, Chun-Liang Sun, Sheng-Li Gu, Chang-Sheng Song, Weng-Dong Hao, Xiao-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Co(C(9)H(9)O(3))(2)(H(2)O)(2)], each Co(II) atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co—O bond lengths = 2.0487 (9) and 2.1090 (9) Å] and two water molecules [Co—O bond length = 2.0873 (9) Å] in a distorted octahedral geometry. In the crystal structure, intermolecular hydrogen bonds and π–π stacking interactions [centroid–centroid distance between phenyl rings = 3.692 (2) Å] link the molecules into a supramolecular structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961700/ /pubmed/21202757 http://dx.doi.org/10.1107/S1600536808016899 Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Chun-Liang Sun, Sheng-Li Gu, Chang-Sheng Song, Weng-Dong Hao, Xiao-Min Diaquabis[2-(benzyloxy)acetato]cobalt(II) |
| title | Diaquabis[2-(benzyloxy)acetato]cobalt(II) |
| title_full | Diaquabis[2-(benzyloxy)acetato]cobalt(II) |
| title_fullStr | Diaquabis[2-(benzyloxy)acetato]cobalt(II) |
| title_full_unstemmed | Diaquabis[2-(benzyloxy)acetato]cobalt(II) |
| title_short | Diaquabis[2-(benzyloxy)acetato]cobalt(II) |
| title_sort | diaquabis[2-(benzyloxy)acetato]cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961700/ https://www.ncbi.nlm.nih.gov/pubmed/21202757 http://dx.doi.org/10.1107/S1600536808016899 |
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