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4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene

The title compound, C(11)H(10)Cl(2), is a useful inter­mediate for the synthesis of 1H-cyclo­propa[b]naphthalene. Strain in the mol­ecule is evidenced by the fact that the cyclo­hexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclo­pro...

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Detalles Bibliográficos
Autores principales: Chen, Wan-Li, Chen, Guo-Sheng, Zhu, Ying-Hong, Mo, Wei-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961701/
https://www.ncbi.nlm.nih.gov/pubmed/21202938
http://dx.doi.org/10.1107/S160053680801831X
Descripción
Sumario:The title compound, C(11)H(10)Cl(2), is a useful inter­mediate for the synthesis of 1H-cyclo­propa[b]naphthalene. Strain in the mol­ecule is evidenced by the fact that the cyclo­hexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclo­propyl ring is almost perpendicular to the cyclo­hexane ring [dihedral angle 70.99 (12)°]. The mol­ecules are loosely connected into one-dimensional chains by inter­molecular Cl⋯Cl inter­actions with a distance of 3.571 (1) Å. The centroid-to-centroid distance between stacked benzene rings is ca 5.89 Å, indicating that no π–π stacking exists in the crystal structure.