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4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene
The title compound, C(11)H(10)Cl(2), is a useful intermediate for the synthesis of 1H-cyclopropa[b]naphthalene. Strain in the molecule is evidenced by the fact that the cyclohexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclopro...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961701/ https://www.ncbi.nlm.nih.gov/pubmed/21202938 http://dx.doi.org/10.1107/S160053680801831X |
Sumario: | The title compound, C(11)H(10)Cl(2), is a useful intermediate for the synthesis of 1H-cyclopropa[b]naphthalene. Strain in the molecule is evidenced by the fact that the cyclohexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclopropyl ring is almost perpendicular to the cyclohexane ring [dihedral angle 70.99 (12)°]. The molecules are loosely connected into one-dimensional chains by intermolecular Cl⋯Cl interactions with a distance of 3.571 (1) Å. The centroid-to-centroid distance between stacked benzene rings is ca 5.89 Å, indicating that no π–π stacking exists in the crystal structure. |
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