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4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene
The title compound, C(11)H(10)Cl(2), is a useful intermediate for the synthesis of 1H-cyclopropa[b]naphthalene. Strain in the molecule is evidenced by the fact that the cyclohexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclopro...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961701/ https://www.ncbi.nlm.nih.gov/pubmed/21202938 http://dx.doi.org/10.1107/S160053680801831X |
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author | Chen, Wan-Li Chen, Guo-Sheng Zhu, Ying-Hong Mo, Wei-Min |
author_facet | Chen, Wan-Li Chen, Guo-Sheng Zhu, Ying-Hong Mo, Wei-Min |
author_sort | Chen, Wan-Li |
collection | PubMed |
description | The title compound, C(11)H(10)Cl(2), is a useful intermediate for the synthesis of 1H-cyclopropa[b]naphthalene. Strain in the molecule is evidenced by the fact that the cyclohexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclopropyl ring is almost perpendicular to the cyclohexane ring [dihedral angle 70.99 (12)°]. The molecules are loosely connected into one-dimensional chains by intermolecular Cl⋯Cl interactions with a distance of 3.571 (1) Å. The centroid-to-centroid distance between stacked benzene rings is ca 5.89 Å, indicating that no π–π stacking exists in the crystal structure. |
format | Text |
id | pubmed-2961701 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617012010-12-30 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene Chen, Wan-Li Chen, Guo-Sheng Zhu, Ying-Hong Mo, Wei-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(10)Cl(2), is a useful intermediate for the synthesis of 1H-cyclopropa[b]naphthalene. Strain in the molecule is evidenced by the fact that the cyclohexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclopropyl ring is almost perpendicular to the cyclohexane ring [dihedral angle 70.99 (12)°]. The molecules are loosely connected into one-dimensional chains by intermolecular Cl⋯Cl interactions with a distance of 3.571 (1) Å. The centroid-to-centroid distance between stacked benzene rings is ca 5.89 Å, indicating that no π–π stacking exists in the crystal structure. International Union of Crystallography 2008-06-21 /pmc/articles/PMC2961701/ /pubmed/21202938 http://dx.doi.org/10.1107/S160053680801831X Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chen, Wan-Li Chen, Guo-Sheng Zhu, Ying-Hong Mo, Wei-Min 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
title | 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
title_full | 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
title_fullStr | 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
title_full_unstemmed | 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
title_short | 4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
title_sort | 4,4-dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961701/ https://www.ncbi.nlm.nih.gov/pubmed/21202938 http://dx.doi.org/10.1107/S160053680801831X |
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