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4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene

The title compound, C(11)H(10)Cl(2), is a useful inter­mediate for the synthesis of 1H-cyclo­propa[b]naphthalene. Strain in the mol­ecule is evidenced by the fact that the cyclo­hexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclo­pro...

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Detalles Bibliográficos
Autores principales: Chen, Wan-Li, Chen, Guo-Sheng, Zhu, Ying-Hong, Mo, Wei-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961701/
https://www.ncbi.nlm.nih.gov/pubmed/21202938
http://dx.doi.org/10.1107/S160053680801831X
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author Chen, Wan-Li
Chen, Guo-Sheng
Zhu, Ying-Hong
Mo, Wei-Min
author_facet Chen, Wan-Li
Chen, Guo-Sheng
Zhu, Ying-Hong
Mo, Wei-Min
author_sort Chen, Wan-Li
collection PubMed
description The title compound, C(11)H(10)Cl(2), is a useful inter­mediate for the synthesis of 1H-cyclo­propa[b]naphthalene. Strain in the mol­ecule is evidenced by the fact that the cyclo­hexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclo­propyl ring is almost perpendicular to the cyclo­hexane ring [dihedral angle 70.99 (12)°]. The mol­ecules are loosely connected into one-dimensional chains by inter­molecular Cl⋯Cl inter­actions with a distance of 3.571 (1) Å. The centroid-to-centroid distance between stacked benzene rings is ca 5.89 Å, indicating that no π–π stacking exists in the crystal structure.
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spelling pubmed-29617012010-12-30 4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene Chen, Wan-Li Chen, Guo-Sheng Zhu, Ying-Hong Mo, Wei-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(10)Cl(2), is a useful inter­mediate for the synthesis of 1H-cyclo­propa[b]naphthalene. Strain in the mol­ecule is evidenced by the fact that the cyclo­hexane ring is essentially planar and nearly coplanar with the benzene ring [dihedral angle 1.87 (18)°], and the cyclo­propyl ring is almost perpendicular to the cyclo­hexane ring [dihedral angle 70.99 (12)°]. The mol­ecules are loosely connected into one-dimensional chains by inter­molecular Cl⋯Cl inter­actions with a distance of 3.571 (1) Å. The centroid-to-centroid distance between stacked benzene rings is ca 5.89 Å, indicating that no π–π stacking exists in the crystal structure. International Union of Crystallography 2008-06-21 /pmc/articles/PMC2961701/ /pubmed/21202938 http://dx.doi.org/10.1107/S160053680801831X Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Wan-Li
Chen, Guo-Sheng
Zhu, Ying-Hong
Mo, Wei-Min
4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
title 4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
title_full 4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
title_fullStr 4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
title_full_unstemmed 4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
title_short 4,4-Dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
title_sort 4,4-dichloro­tricyclo­[5.4.0.0(3,5)]undeca-7,9,11-triene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961701/
https://www.ncbi.nlm.nih.gov/pubmed/21202938
http://dx.doi.org/10.1107/S160053680801831X
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