Benzamidinium tetra­hydro­penta­borate sesquihydrate

The asymmetric unit of the title compound [systematic name: benzamidinium 3,3′,5,5′-tetra­hydr­oxy-1,1′-spirobi[2,4,6-trioxa-1,3,5-triboracyclo­hexa­ne](1−) sesquihydrate], C(7)H(9)N(2) (+)·B(5)H(4)O(10) (−)·1.5H(2)O, is composed of two protonated benzamidinium cations, two tetra­hydro­penta­borate...

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Detalles Bibliográficos
Autor principal: Portalone, Gustavo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961702/
https://www.ncbi.nlm.nih.gov/pubmed/21202914
http://dx.doi.org/10.1107/S1600536808017522
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author Portalone, Gustavo
author_facet Portalone, Gustavo
author_sort Portalone, Gustavo
collection PubMed
description The asymmetric unit of the title compound [systematic name: benzamidinium 3,3′,5,5′-tetra­hydr­oxy-1,1′-spirobi[2,4,6-trioxa-1,3,5-triboracyclo­hexa­ne](1−) sesquihydrate], C(7)H(9)N(2) (+)·B(5)H(4)O(10) (−)·1.5H(2)O, is composed of two protonated benzamidinium cations, two tetra­hydro­penta­borate anions and three water mol­ecules of crystallization. The ions and water molecules are associated in the crystal structure by an extensive three-dimensional hydrogen-bonding network, which consists mainly of cation-to-anion N—H⋯O and anion-to-anion O—H⋯O hydrogen bonds.
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spelling pubmed-29617022010-12-30 Benzamidinium tetra­hydro­penta­borate sesquihydrate Portalone, Gustavo Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound [systematic name: benzamidinium 3,3′,5,5′-tetra­hydr­oxy-1,1′-spirobi[2,4,6-trioxa-1,3,5-triboracyclo­hexa­ne](1−) sesquihydrate], C(7)H(9)N(2) (+)·B(5)H(4)O(10) (−)·1.5H(2)O, is composed of two protonated benzamidinium cations, two tetra­hydro­penta­borate anions and three water mol­ecules of crystallization. The ions and water molecules are associated in the crystal structure by an extensive three-dimensional hydrogen-bonding network, which consists mainly of cation-to-anion N—H⋯O and anion-to-anion O—H⋯O hydrogen bonds. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961702/ /pubmed/21202914 http://dx.doi.org/10.1107/S1600536808017522 Text en © Gustavo Portalone 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Portalone, Gustavo
Benzamidinium tetra­hydro­penta­borate sesquihydrate
title Benzamidinium tetra­hydro­penta­borate sesquihydrate
title_full Benzamidinium tetra­hydro­penta­borate sesquihydrate
title_fullStr Benzamidinium tetra­hydro­penta­borate sesquihydrate
title_full_unstemmed Benzamidinium tetra­hydro­penta­borate sesquihydrate
title_short Benzamidinium tetra­hydro­penta­borate sesquihydrate
title_sort benzamidinium tetra­hydro­penta­borate sesquihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961702/
https://www.ncbi.nlm.nih.gov/pubmed/21202914
http://dx.doi.org/10.1107/S1600536808017522
work_keys_str_mv AT portalonegustavo benzamidiniumtetrahydropentaboratesesquihydrate

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