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5-Isopropyl-2-methyl-3-phenylsulfonyl-1-benzofuran
The title compound, C(18)H(18)O(3)S, was prepared by the oxidation of 5-isopropyl-2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 79.37 (6)° with the plane of the benzofuran fragment. The crystal structure is stabilized by aromatic...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961705/ https://www.ncbi.nlm.nih.gov/pubmed/21202891 http://dx.doi.org/10.1107/S1600536808017224 |
Sumario: | The title compound, C(18)H(18)O(3)S, was prepared by the oxidation of 5-isopropyl-2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 79.37 (6)° with the plane of the benzofuran fragment. The crystal structure is stabilized by aromatic π–π stacking interactions between the benzene and furan rings of neighbouring molecules [centroid–centroid distance = 3.762 (3) Å]. In addition, the stacked molecules exhibit C—H⋯π and intramolecular C—H⋯O interactions. |
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