N-(2,6-Dimethyl­phen­yl)benzamide

The title compound, C(15)H(15)NO, crystallizes with two mol­ecules in the asymmetric unit. The H—N—C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl­phen­yl)benzamide, N-(2,6-dichloro­phen­yl)benz­amide and other benzanilides. The central –NHCO– bridging unit is tilt...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961710/
https://www.ncbi.nlm.nih.gov/pubmed/21202928
http://dx.doi.org/10.1107/S1600536808018230
Descripción
Sumario:The title compound, C(15)H(15)NO, crystallizes with two mol­ecules in the asymmetric unit. The H—N—C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl­phen­yl)benzamide, N-(2,6-dichloro­phen­yl)benz­amide and other benzanilides. The central –NHCO– bridging unit is tilted at angles of 17.1 (3) and 16.4 (3)° to the benzoyl ring in the two mol­ecules. The two rings (benzoyl and aniline) are almost orthogonal with respect to each other, making dihedral angles of 86.3 (1) and 86.0 (1)° in the two mol­ecules. N—H⋯O hydrogen bonds link mol­ecules into infinite chains running along the c axis.

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