N-(2,6-Dimethyl­phen­yl)benzamide

The title compound, C(15)H(15)NO, crystallizes with two mol­ecules in the asymmetric unit. The H—N—C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl­phen­yl)benzamide, N-(2,6-dichloro­phen­yl)benz­amide and other benzanilides. The central –NHCO– bridging unit is tilt...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961710/
https://www.ncbi.nlm.nih.gov/pubmed/21202928
http://dx.doi.org/10.1107/S1600536808018230
_version_ 1782189047535370240
author Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The title compound, C(15)H(15)NO, crystallizes with two mol­ecules in the asymmetric unit. The H—N—C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl­phen­yl)benzamide, N-(2,6-dichloro­phen­yl)benz­amide and other benzanilides. The central –NHCO– bridging unit is tilted at angles of 17.1 (3) and 16.4 (3)° to the benzoyl ring in the two mol­ecules. The two rings (benzoyl and aniline) are almost orthogonal with respect to each other, making dihedral angles of 86.3 (1) and 86.0 (1)° in the two mol­ecules. N—H⋯O hydrogen bonds link mol­ecules into infinite chains running along the c axis.
format Text
id pubmed-2961710
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29617102010-12-30 N-(2,6-Dimethyl­phen­yl)benzamide Gowda, B. Thimme Tokarčík, Miroslav Kožíšek, Jozef Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(15)NO, crystallizes with two mol­ecules in the asymmetric unit. The H—N—C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl­phen­yl)benzamide, N-(2,6-dichloro­phen­yl)benz­amide and other benzanilides. The central –NHCO– bridging unit is tilted at angles of 17.1 (3) and 16.4 (3)° to the benzoyl ring in the two mol­ecules. The two rings (benzoyl and aniline) are almost orthogonal with respect to each other, making dihedral angles of 86.3 (1) and 86.0 (1)° in the two mol­ecules. N—H⋯O hydrogen bonds link mol­ecules into infinite chains running along the c axis. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961710/ /pubmed/21202928 http://dx.doi.org/10.1107/S1600536808018230 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Sowmya, B. P.
Fuess, Hartmut
N-(2,6-Dimethyl­phen­yl)benzamide
title N-(2,6-Dimethyl­phen­yl)benzamide
title_full N-(2,6-Dimethyl­phen­yl)benzamide
title_fullStr N-(2,6-Dimethyl­phen­yl)benzamide
title_full_unstemmed N-(2,6-Dimethyl­phen­yl)benzamide
title_short N-(2,6-Dimethyl­phen­yl)benzamide
title_sort n-(2,6-dimethyl­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961710/
https://www.ncbi.nlm.nih.gov/pubmed/21202928
http://dx.doi.org/10.1107/S1600536808018230
work_keys_str_mv AT gowdabthimme n26dimethylphenylbenzamide
AT tokarcikmiroslav n26dimethylphenylbenzamide
AT kozisekjozef n26dimethylphenylbenzamide
AT sowmyabp n26dimethylphenylbenzamide
AT fuesshartmut n26dimethylphenylbenzamide

Ejemplares similares