Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate

In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa­hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro­benzoic acid mol­ecules...

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Detalles Bibliográficos
Autores principales: Hu, Fei-Long, Yin, Xian-Hong, Luo, Wei-Qiang, Zhao, Kai, Lin, Cui-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961712/
https://www.ncbi.nlm.nih.gov/pubmed/21202753
http://dx.doi.org/10.1107/S1600536808016759
Descripción
Sumario:In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa­hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro­benzoic acid mol­ecules is linked to the mol­ecule of the complex via a hydrogen bond involving its carboxylic H atom and one of the DMPP ligands of the complex. However, in one of the DMPP ligands, the non-coordinated carbonyl O atom serves as the hydrogen-bond acceptor, whereas in the second ligand it is the Mn-coordinated O atom which is involved in the hydrogen bonding.

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