Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate

In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa­hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro­benzoic acid mol­ecules...

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Autores principales: Hu, Fei-Long, Yin, Xian-Hong, Luo, Wei-Qiang, Zhao, Kai, Lin, Cui-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961712/
https://www.ncbi.nlm.nih.gov/pubmed/21202753
http://dx.doi.org/10.1107/S1600536808016759
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author Hu, Fei-Long
Yin, Xian-Hong
Luo, Wei-Qiang
Zhao, Kai
Lin, Cui-Wu
author_facet Hu, Fei-Long
Yin, Xian-Hong
Luo, Wei-Qiang
Zhao, Kai
Lin, Cui-Wu
author_sort Hu, Fei-Long
collection PubMed
description In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa­hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro­benzoic acid mol­ecules is linked to the mol­ecule of the complex via a hydrogen bond involving its carboxylic H atom and one of the DMPP ligands of the complex. However, in one of the DMPP ligands, the non-coordinated carbonyl O atom serves as the hydrogen-bond acceptor, whereas in the second ligand it is the Mn-coordinated O atom which is involved in the hydrogen bonding.
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spelling pubmed-29617122010-12-30 Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate Hu, Fei-Long Yin, Xian-Hong Luo, Wei-Qiang Zhao, Kai Lin, Cui-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa­hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro­benzoic acid mol­ecules is linked to the mol­ecule of the complex via a hydrogen bond involving its carboxylic H atom and one of the DMPP ligands of the complex. However, in one of the DMPP ligands, the non-coordinated carbonyl O atom serves as the hydrogen-bond acceptor, whereas in the second ligand it is the Mn-coordinated O atom which is involved in the hydrogen bonding. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961712/ /pubmed/21202753 http://dx.doi.org/10.1107/S1600536808016759 Text en © Hu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Fei-Long
Yin, Xian-Hong
Luo, Wei-Qiang
Zhao, Kai
Lin, Cui-Wu
Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate
title Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate
title_full Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate
title_fullStr Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate
title_full_unstemmed Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate
title_short Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))picolinato-κ(2) N,O]manganese(II) bis­(3,5-dinitro­benzoic acid) solvate
title_sort bis[6-(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))picolinato-κ(2) n,o]manganese(ii) bis­(3,5-dinitro­benzoic acid) solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961712/
https://www.ncbi.nlm.nih.gov/pubmed/21202753
http://dx.doi.org/10.1107/S1600536808016759
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